| 用于脱除C5及MTBE中甲醇的渗透汽化膜研究 |
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| 引用本文： | 张林,陈欢林,周志军,钱锦文,高从堦,潘祖仁.用于脱除C5及MTBE中甲醇的渗透汽化膜研究[J].中国化学工程学报,2003,11(2):156-161. |
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| 作者姓名： | 张林 陈欢林 周志军 钱锦文 高从堦 潘祖仁 |
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| 作者单位： | College of Material Science & Chemical Engineering，Zhejiang University，College of Material Science & Chemical Engineering，Zhejiang University，College of Material Science & Chemical Engineering，Zhejiang University，College of Material Science & Chemical Engineering，Zhejiang University，Development Center of Water Treatment Technology，College of Material Science & Chemical Engineering，Zhejiang University Hangzhou 310027，China，Hangzhou 310027，China，Hangzhou 310027，China，Hangzhou 310027，China，SOA，Hangzhou 310012，China，Hangzhou 310027，China |
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| 基金项目： | Supported by the National NaturM Science Foundation of China(No.29836160). |
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| 摘 要： | Several pervaporation membranes, cellulose acetate (CA), polyvinylbutyral (PVB), poly(MMA-co-AA), MMA-AA-BA, CA/PVB blend and CA/poly(MMA-co-AA) blend, were prepared, and their pervaporation properties were evaluated by separation of methanol/C5 or methanol/MTBE (methyl tert-butyl ether). The results shows that the CA composite membrane has a high separation performance (flux Jmenthanol =350g.m-2.h-1 and separation factor a > 400) for methanol/C5 mixtures, and the pervaporation characteristics of MMA-AA-BA copolymer membranes changes with the ratio of copolymer. For CA/poly(MMA-co-AA) blend membrane, the pervaporation performance is improved in comparison with CA or poly(MMA-co-AA) membrane. From the experiment of CA/PVB blend membranes for methanol/MTBE mixture, it is found that the compatibility of blends may affect the separation features of blend membrane.
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| 关 键 词： | 聚乙烯 MTBE 甲醇 渗透汽化膜 烃 膜分离 |
| 修稿时间： | |
Study on Pervaporation Membranes for Removing Methanol from C5 or Methyl Tert-butyl Ether Mixtures |
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| ZHANG Lin,CHEN Huanlin,ZHOU Zhijun,QIAN Jinwen,GAO Congjie,PAN Zuren.Study on Pervaporation Membranes for Removing Methanol from C5 or Methyl Tert-butyl Ether Mixtures[J].Chinese Journal of Chemical Engineering,2003,11(2):156-161. |
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| Authors: | ZHANG Lin CHEN Huanlin ZHOU Zhijun QIAN Jinwen GAO Congjie PAN Zuren |
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| Affiliation: | College of Material Science & Chemical Engineering, Zhejiang University, Hangzhou 310027, China Development Center of Water Treatment Technology, SOA, Hangzhou 310012, China |
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| Abstract: | Several pervaporation membranes, cellulose acetate (CA), polyvinylbutyral (PVB), poly(MMA-co-AA), MMA-AA-BA, CA/PVB blend and CA/poly(MMA-co-AA) blend, were prepared, and their pervaporation properties were evaluated by separation of methanol/C5 or methanol/MTBE (methyl tert-butyl ether). The results shows that the CA composite membrane has a high separation performance (flux Jmenthanol =350g.m-2.h-1 and separation factor a > 400) for methanol/C5 mixtures, and the pervaporation characteristics of MMA-AA-BA copolymer membranes changes with the ratio of copolymer. For CA/poly(MMA-co-AA) blend membrane, the pervaporation performance is improved in comparison with CA or poly(MMA-co-AA) membrane. From the experiment of CA/PVB blend membranes for methanol/MTBE mixture, it is found that the compatibility of blends may affect the separation features of blend membrane. |
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| Keywords: | pervaporation membrane methanol C5 methyl tert-butyl ether blend |
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