|
|||||
|
|
| 有机胺吸收燃煤烟气CO2中抗氧化剂的作用机理研究 | |
| 引用本文： | 季芹芹,刘建周,张亚萍,罗红情,朱刚,江晶亮,许红娟. 有机胺吸收燃煤烟气CO2中抗氧化剂的作用机理研究[J]. 中国煤炭, 2012, 38(5): 113-117 |
| 作者姓名： | 季芹芹 刘建周 张亚萍 罗红情 朱刚 江晶亮 许红娟 |
| 作者单位： | 1. 中国矿业大学化工学院,江苏省徐州市,221116 2. 中国矿业大学化工学院,江苏省徐州市,221116;中国矿业大学江苏省煤基CCS重点实验室,江苏省徐州市,221008 3. 中国矿业大学化工学院,江苏省徐州市,221116;山东荣信煤化有限公司,山东省济宁市,272000 4. 上海锅炉厂有限公司,上海闵行区,200245 5. 上海电气集团上海电机厂有限公司,上海闵行区,200240 |
| 基金项目： | 中国矿业大学江苏省煤基CO2捕集与地质储存重点实验室开放基金，国家自然科学研究基金，江苏省普通高校研究生科研创新计划资助项目 |
| 摘 要： | 以乙醇胺(MEA)为吸收剂,吸收燃煤电厂烟气中的CO2,在吸收剂中添加抗氧剂1010(四[β-(3,5-二叔丁基-4-羟基苯基)丙酸]季戊四醇酯)以减缓MEA的氧化降解。研究了抗氧剂1010的添加量对MEA吸收CO2的吸收速率和吸收量的影响,应用红外分析仪对MEA的氧化产物进行了分析,探讨抗氧剂对MEA的抗氧化机理,结果表明抗氧剂1010能够有效降低MEA的氧化降解,当抗氧剂用量为吸收剂用量的0.15%时,吸收剂会保持较大的吸收容量和较快的吸收速率。 |
| 关 键 词： | MEA 氧化降解 抗氧剂1010 二氧化碳吸收剂 |
The mechanism of antioxidant on the absorption of CO2 from flue gas by organic amine |
|
| Ji Qinqin , Liu Jianzhou , Zhang Yaping , Luo Hongqing , Zhu Gang , Jiang Jingliang , Xu Hongjuan. The mechanism of antioxidant on the absorption of CO2 from flue gas by organic amine[J]. China Coal, 2012, 38(5): 113-117 | |
| Authors: | Ji Qinqin Liu Jianzhou Zhang Yaping Luo Hongqing Zhu Gang Jiang Jingliang Xu Hongjuan |
| Affiliation: | 1.School of Chemical Engineering and Technology,CUMT,Xuzhou,Jiangsu 221116,China; 2.Jiangsu Province Coal Based CCS Key Laboratories,Xuzhou,Jiangsu 221116,China; 3.Shandong Rongxin Coking Group,Jining,Shandong 272000,China; 4.Shanghai Boiler Plant Co.,LTD,Minhang,Shanghai 200245,China; 5.Shanghai Electric Group Shanghai Electric Co.,LTD,Minhang,Shanghai 200240,China) |
| Abstract: | In this study,using MEA as absorbent to absorb CO2 of flue gas.Antioxidant 1010(4[β-(3,5-di-tert-butyl-4-hydroxyphenyl)propionic acid]pentaerythritol) was added to decrease the oxidative degradation of MEA.This study included researching how the addition of antioxidant 1010 affect the absorption rate and capacity of CO2,analyzed MEA oxidation products by using infrared analyzer,and discussed MEA antioxidant mechanism.The result showed that antioxidant 1010 effectively reduces the oxidative degradation of MEA.When the antioxidant amount is 0.15% of the amount of absorbent,the absorbent will maintain a large absorption capacity and faster absorption rate. |
| Keywords: | MEA oxidative degradation antioxidant 1010 carbon dioxide absorber |
| 本文献已被 CNKI 万方数据 等数据库收录！ | |