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Cadmium sulfide nanotubes thin films: Characterization and photoelectrochemical behavior
Authors:Chenhuan Li
Affiliation:
  • a College of Chemical Engineering, Sichuan University, Chengdu 610065, China
  • b China Academy of Engineering Physics, Mianyang 621900, China
  • c Key laboratory of Green Chemistry and Technology, Ministry of Education, College of Chemistry , Sichuan University, Chengdu 610065, China
  • Abstract:Monodisperse cadmium sulfide nanotubes (CdS NTs) with a diameter of 100 nm were synthesized on indium-doped tin oxide glass substrates using chemical bath deposition and self-sacrificial template technique. This CdS thin film was characterized by transmission electron microscope, scanning electron microscope, X-ray diffraction, X-ray photoelectron spectroscopy and UV-vis spectrophotometer. This film gave a short circuit photocurrent of 4.4 mA/cm2, an open circuit photovoltage of 0.75 V, a fill factor of 0.49, and an overall conversion efficiency of 1.29% under a simulated solar illumination of 100 mW/cm2. All these photoelectrochemical properties of the films were dependent on the microstructure of the nanotubes and the thickness of the film. A facile and efficient way to prepare CdS-based photoelectrodes for photoelectrochemical cells was provided in this report.
    Keywords:Cadmium sulfide   Nanotubes   Chemical bath deposition   Sacrificial templates   Photoelectrochemical properties   X-ray diffraction   Scanning electron microscopy
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