| 微波照射硫酸氢钠催化合成环己酮乙二醇缩酮 |
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| 引用本文： | 刘勇,王俏,郭延红.微波照射硫酸氢钠催化合成环己酮乙二醇缩酮[J].化学与粘合,2008,30(6):74-76. |
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| 作者姓名： | 刘勇 王俏 郭延红 |
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| 作者单位： | 延安职业技术学院;延安大学化学与化工学院; |
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| 摘 要： | 在微波辐射下，以硫酸氢钠为催化剂，环己烷为带水剂，合成了环己酮乙二醇缩酮。考察了催化剂的用量、反应时间、酮醇物质的量之比、带水剂的用量及微波功率等诸多因素对产品收率的影响。实验表明，固定环己酮0．2mol，在n（环己酮）：n（乙二醇）=1．0：1．5，催化剂用量为1．55g，带水剂环己烷为12mL，反应温度135℃，微波功率为500W和反应时间为25min的优化条件下，环己酮乙二醇缩酮的收率可达78．2％。
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| 关 键 词： | 微波辐射 环己酮乙二醇缩酮 硫酸氢钠 催化合成 缩酮反应 |
Synthesis of Cyclohexanone Glycol Ketal Catalyzed by Sodium Hydrogen Sulfate under Microwave Irradiation |
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| LIU Yong,WANG Qiao,GUO Yan-hong.Synthesis of Cyclohexanone Glycol Ketal Catalyzed by Sodium Hydrogen Sulfate under Microwave Irradiation[J].Chemistry and Adhesion,2008,30(6):74-76. |
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| Authors: | LIU Yong WANG Qiao GUO Yan-hong |
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| Affiliation: | LIU Yong , WANG Qiao, GUO Yan- hong (1. Yanan Vocation Technological College, Yanan 716000, China; 2. Department of Chemistry and Chemistry Engineering, Yanan Univeristy, Yanan 716000, China) |
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| Abstract: | This product was prepared with using cyclohexane as the water carrying agent. The effect factors on the yield were discussed, such as material ratio, water -carrying agent amount, catalyst dosage, microwave irradiation power and time, etc. And the optimal reaction conditions were gained. When cyclohexanone is 0.2mol, the molar ratio of n （cyclohexanone）： n （glycol） is 1： 1.5, the microwave irradiation power is 500W, the catalyst amount is 1.55g, the water- carrying agent（cyclohexane） is 12mL, and reacts at 135℃ for 25min, the yield of cyclohexanone glycol ketal can reach 78.2%. |
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| Keywords: | Microwave irradiation cyclohexanone glycol ketal sodium hydrogen sulfate catalytic synthesis ketal reaction |
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