Enhanced DSSC performance with high surface area thin anatase TiO2 nanoleaves |
| |
Authors: | Vivek Dhas Shruti Agarkar Beatrice Hannoyer Satishchandra Ogale |
| |
Affiliation: | a National Chemical Laboratory, Council of Scientific and Industrial Research, Pune 411 008, India b Université de Rouen, GPM UMR 6634 CNRS - BP 12, 76801 Etienne du Rouvray Cedex, France |
| |
Abstract: | Thin anatase TiO2 nanoleaves (NLs) with high surface area (∼93 m2/g) are synthesized by hydrothermal route and dye-sensitized solar cells (DSSC) made using such NLs are compared with those made with hydro-thermally synthesized TiO2 nanoparticles and the Degussa P25 powder. The NLs-based DSSCs show increment of 16% and 24% in the total conversion efficiency over the cells made with NPs and P25 respectively. Interestingly, the highest increment in the conversion efficiency (∼35%) is achieved for cells made using a 50:50 (wt/wt) mixture of NLs and NPs. In this case the dye loading is found to be >50% higher than the case of NP films. Moreover the DC resistance of diffusion of in electrolyte (as revealed by the electrochemical impedance spectroscopy) is substantially lower than the NP film case, other cell parameters being nominally comparable. |
| |
Keywords: | Dye-sensitized solar cells Hydrothermal Electrochemical impedance spectroscopy |
本文献已被 ScienceDirect 等数据库收录! |