| 固体超强酸SO42-/TiO2-Fe2O3催化合成柠檬酸三丁酯 |
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| 引用本文： | 姜业朝,陈伟,冯树林. 固体超强酸SO42-/TiO2-Fe2O3催化合成柠檬酸三丁酯[J]. 重庆科技学院学报(社会科学版), 2001, 16(3): 27-29 |
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| 作者姓名： | 姜业朝 陈伟 冯树林 |
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| 作者单位： | 1. 扬州化工学校,扬州,225007
2. 扬州宝胜生化有限公司 |
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| 摘 要： | 制备固体酸催化剂SO42-/TiO2-Fe2O3,用于柠檬酸三正丁酯的合成试验.考察了反应时间、初始进料物质的量比、催化剂用量对反应产率的影响,反应最佳条件为:醇酸比6:1,催化剂用量2.0g(相对于0.1mol的柠檬酸),加热回流反应时间3h,转化率达94.5%,纯度大于99.0%.
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| 关 键 词： | SO42-/TiO2-Fe2O3复合固体超强酸 催化剂 合成 |
| 文章编号： | 1009-3494(2001)03-0027-03 |
| 修稿时间： | 2001-05-26 |
Synthesis of Tri-n- Butyl Citrate by the Composite Solid Superacid SO24-/TiO2- Fe2O3 |
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| Jiang Yechao,Chen Wei,Feng Shuling. Synthesis of Tri-n- Butyl Citrate by the Composite Solid Superacid SO24-/TiO2- Fe2O3[J]. JOURNAL OF CHONGQING UNIVERSITY OF SCEENCE AND TECHNOLOGY, 2001, 16(3): 27-29 |
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| Authors: | Jiang Yechao Chen Wei Feng Shuling |
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| Abstract: | The solid acid catalyst SO 2- 4/TiO 2- Fe 2O 3 was prepared and its catalytic properties for the synthesis of tri-n-butyl citrate has been tested. The effects of reaction time, initial molar ratio and catalyst quantity on reaction conversion have been studied. The proper technology parameters for the process are achieved: the molar ratio of butanol to citric acid is 6:1, weight of catalyst was 2.0g (weight of 0.1mol citric acid), the reaction time was 3 hours under stirring and refluxing, then the conversion of citric acid is above 94.5%, and the purity of resulting product is over 99%. |
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| Keywords: | Composite Solid Superacid SO 2- 4/TiO 2- Fe 2O 3 catalyst synthesis |
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