| 己二酸的清洁催化氧化合成研究进展 |
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| 引用本文： | 赵建波,桂阳海,刘应凡,谢冰,郑先君,孙晓丽,孙雨安.己二酸的清洁催化氧化合成研究进展[J].郑州轻工业学院学报(自然科学版),2011,26(2):45-49. |
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| 作者姓名： | 赵建波 桂阳海 刘应凡 谢冰 郑先君 孙晓丽 孙雨安 |
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| 作者单位： | 郑州轻工业学院河南省表界面科学重点实验室,河南,郑州,450002 |
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| 基金项目： | 河南省教育厅自然科学基金项目，郑州轻工业学院校内科研基金项目 |
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| 摘 要： | 综述了近年来以环己烯、环己酮、环己醇或环己烷等作原料,以过氧化氢或氧气等为氧源,采用不同的催化体系清洁合成己二酸的新进展.指出:在这些方法中,改性的分子筛及负载型催化剂-双氧水体系将是今后己二酸清洁合成的重点研究方向.
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| 关 键 词： | 己二酸 催化氧化 清洁合成 过氧化氢 环己烯 |
Progress in clean catalytic oxidation synthesis of adipic acid |
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| ZHAO Jian-bo,GUI Yang-hai,LIU Ying-fan,ME Bing,ZHENG Man-jun,SUN Xiao-li,SUN Yu-an.Progress in clean catalytic oxidation synthesis of adipic acid[J].Journal of Zhengzhou Institute of Light Industry(Natural Science),2011,26(2):45-49. |
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| Authors: | ZHAO Jian-bo GUI Yang-hai LIU Ying-fan ME Bing ZHENG Man-jun SUN Xiao-li SUN Yu-an |
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| Affiliation: | (He′nan Key Lab.of Surface & Interface Sci.,Zhengzhou Univ.of Light Ind.,Zhengzhou 450002,China) |
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| Abstract: | Recent developments on clean synthesis of adipic acid in the presence of different catalytic systems were reviewed,in which cyclohexene,cyclohexone,cyclohexanol or cyclohexane are used as substrate and hydrogen peroxide or oxygen as clean oxidant.Based on these discussions,the modified zeolite and supported catalyst-hydrogen peroxide systems will be a main direction for the clean synthesis of adipic acid in the future. |
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| Keywords: | adipic acid catalytic oxidation clean synthesis hydrogen peroxide cyclohexene |
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