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AgX光色玻璃退色动力学模型
引用本文:刘彤,沈菊云,陈学贤,缪之训. AgX光色玻璃退色动力学模型[J]. 无机材料学报, 2000, 15(2): 254-258
作者姓名:刘彤  沈菊云  陈学贤  缪之训
作者单位:中国科学院上海硅酸盐研究所, 上海 200050
摘    要:以AgX光色玻璃中的胶体Ag转化为Ag的转化几率b为基础,推导了AgX光色玻璃的退色动力学模型:T=1—B—kCexp(-bt),并结合实测的退色动力学参数给出了这一模型的数学解法,并将根据该理论模型绘制的退色动力学曲线与实测的退色动力学曲线进行了对比.结果表明:根据AgX光色玻璃中的转化几率b所推导出的退色动力学模型,较好地解释了AgX光色玻璃的退色过程,转化几率b较准确地表征了退包动力学的退色速度,理论计算的退色动力学曲线与实测的退色动力学曲线完全吻合.这进一步证明了本文提出的退色动力学模型及其所依赖的理论基础的正确性.

关 键 词:光色玻璃  AgX  退色动力学模型  
文章编号:CN31-1363(2000)02-0254-05
收稿时间:1999-04-19
修稿时间:1999-04-19

Fading Kinetics Model of Photochromic Glass Containing AgX
LIU Tong,SHEN Ju-Yun,CHEN Xue-xian,MIAO Zhi-Xun. Fading Kinetics Model of Photochromic Glass Containing AgX[J]. Journal of Inorganic Materials, 2000, 15(2): 254-258
Authors:LIU Tong  SHEN Ju-Yun  CHEN Xue-xian  MIAO Zhi-Xun
Affiliation:Shanghai Institute of Ceramics; Chinese Academy of Sciences; Shanghai 200050; China
Abstract:A fading kinetics model, T = 1-B-kC0exp(-bt), was deduced on the basis of transition probability, b, of silver colloid forming silver ion, the solutions of the model were given by applying the measured fading kinetics parameters with a computer, and the measured fading kinetics curves and the calculated fading kinetics curves of F-series photochromic glass containing AgX were compared. The results indicate that the fading kinetics model preferably explains the fading process of the photochromic glass, and the transition probability, b, accurately expresses fading rate of fading kinetics. The calculated curves and measured curves of fading kinetics of F-series photochromic glasses containing AgX are almost similar. So these results further prove that the fading kinetics model is effective to explain the fading process, and the theory as the basis of the fading model is correct.
Keywords:photochromic glass  AgX  kinetics model  fading
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