| 气体分离炭膜的结构设计、制备及功能化 |
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| 引用本文： | 李琳,王同华,曹义鸣,邱介山. 气体分离炭膜的结构设计、制备及功能化[J]. 无机材料学报, 2010, 25(5): 449-456. DOI: 10.3724/SP.J.1077.2010.00449 |
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| 作者姓名： | 李琳 王同华 曹义鸣 邱介山 |
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| 作者单位： | 1. 大连理工大学 化工学院 材料化工系 精细化工国家重点实验室 炭素材料实验室, 大连 116012； 2. 中国科学院 大连化学物理研究所，大连 116023 |
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| 基金项目： | 国家自然科学基金面上与重点项目(20776024,20976021,20836006); 国家863项目(2009AA03Z215) |
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| 摘 要： | 气体渗透性低、机械强度差是炭膜产业化道路上的两大难题.研究发现,根源在于炭膜的蠕虫状孔道结构与均质炭膜的特有性质.为了解决炭膜渗透性低的问题,通过选择适宜的聚合物前驱体的分子结构与空间构型结合填充纳米粒子为功能基团等手段,实现对炭膜蠕虫状孔结构有效地调控与重新构建.在保证高选择性的条件下,不仅使炭膜的气体渗透性能提高了2个数量级以上,而且还使炭膜对某些气体具有较高分离选择性的功能化效果.为了改善炭膜的机械强度,将自主研发的廉价煤基炭膜支撑体与前驱体相复合,采用简单的制膜工艺,制备得到复合性能好、气体分离性能高的复合炭膜.
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| 关 键 词： | 炭膜 功能化 气体分离 复合炭膜 |
| 收稿时间： | 2009-07-01 |
| 修稿时间： | 2009-12-16 |
Physical Design,Preparation and Functionalization of Carbon Membranes for Gas Separation |
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| LI Lin,WANG Tong-Hua,CAO Yi-Ming,QIU Jie-Shan. Physical Design,Preparation and Functionalization of Carbon Membranes for Gas Separation[J]. Journal of Inorganic Materials, 2010, 25(5): 449-456. DOI: 10.3724/SP.J.1077.2010.00449 |
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| Authors: | LI Lin WANG Tong-Hua CAO Yi-Ming QIU Jie-Shan |
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| Affiliation: | 1.Carbon Research Laboratory, State Key Laboratory of Fine Chemicals, Department of Materials Science and Chemical Engineering, School of Chemical Engineering, Dalian University of Technology, Dalian 116012, China; 2.Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China |
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| Abstract: | Two challenges faced by carbon membrane for application on commercial scale are its low permeability and poor mechanical strength.And it is attributed to the vermiform pore structures and special characteristics of carbon membranes.In order to solve these problems,methods such as choosing the precursors with suitable chemical structure and space mould,incorporating nano-size functional groups into precursors are employed to effectively change and improve the vermiform pore structures of carbon membranes and... |
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| Keywords: | carbon membrane functionalization gas separation composite carbon membrane |
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