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Photocatalytic properties of two-dimensional graphene and layered transition-metal dichalcogenides based photocatalyst for photoelectrochemical hydrogen generation: An overview
Affiliation:1. Fuel Cell Institute, Universiti Kebangsaan Malaysia, 43600 UKM Bangi, Selangor, Malaysia;2. School of Chemical Sciences and Food Technology, Faculty of Science and Technology, Universiti Kebangsaan Malaysia, 43600 UKM Bangi, Selangor, Malaysia;1. Solar Hydrogen Group, Fuel Cell Institute (SELFUEL), Universiti Kebangsaan Malaysia, 43600, UKM, Bangi, Selangor, Malaysia;2. School of Chemical Sciences and Food Technology, Faculty of Science and Technology, Universiti Kebangsaan Malaysia, 43600, UKM, Bangi, Selangor, Malaysia;3. Sustainable Construction Materials and Building Systems (SUCOMBS) Research Group, Faculty of Engineering and Built Environment, Universiti Kebangsaan Malaysia, 43600, Bangi, Malaysia;4. Department of Chemical Engineering, Faculty of Chemical and Energy Engineering, Universiti Teknologi Malaysia, 81310, UTM, Skudai, Johor Baharu, Johor, Malaysia;5. Advanced Membrane Technology Research Centre (AMTEC), Universiti Teknologi Malaysia, 81310, Skudai, Johor Darul Takzim, Malaysia;6. Materials Synthesis and Characterization Laboratory, Institute of Advanced Technology, Universiti Putra Malaysia, 43400, Serdang, Selangor, Malaysia;1. Fuel Cell Institute, Universiti Kebangsaan Malaysia, 43600 UKM Bangi, Selangor, Malaysia;2. School of Applied Physics, Faculty of Science and Technology, Universiti Kebangsaan Malaysia, 43600 UKM Bangi, Selangor, Malaysia;3. School of Chemical Sciences and Food Technology, Faculty of Science and Technology, Universiti Kebangsaan Malaysia, 43600 UKM Bangi, Selangor, Malaysia;1. Department of Chemical Engineering, MBM Engineering College, Jai Narain Vyas University, Jodhpur 342011, India;2. Department of Chemical & Life Science Engineering, Virginia Commonwealth University, Richmond, VA 23284, USA
Abstract:Hydrogen production through photoelectrochemical (PEC) water-splitting process has drawn significant research attention because it is a promising clean source of energy for improving earth climate in the future. Two-dimensional (2D) graphene and transition metal dichalcogenides (TMDCs), as the core of the system, have become versatile materials for the development of photocatalyst due to their distinct optical, electrical, thermal and mechanical properties. TMDCs have received significant consideration because of low-cost and earth-abundant catalysts that can replace noble metals, such as Pt. Therefore, comprehensive discussions on the structure and properties of 2D graphene and layered TMDCs materials are presented. We also gather and review various fabrication methods for TMDCs-based and graphene-TMDCs-based photocatalysts that can affect the PEC performance and hydrogen evolution. The inherent limitations and several future trends on 2D graphene and layered TMDCs-based photocatalyst for PEC water-splitting application are also discussed.
Keywords:Graphene  Transition-metal dichalcogenides  2D photocatalyst  Photocatalysis  Water splitting
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