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尼龙6/POE/粘土纳米复合材料的形态、结构及性能研究
引用本文:张成责,孙春红,张晓静,贾天刚,李亚东. 尼龙6/POE/粘土纳米复合材料的形态、结构及性能研究[J]. 材料导报, 2009, 23(14)
作者姓名:张成责  孙春红  张晓静  贾天刚  李亚东
作者单位:郑州轻工业学院材料与化学工程学院,河南省表界面材料重点实验室,郑州,450002
基金项目:国家自然科学基金,河南省教育厅自然科学研究计划项目 
摘    要:采用熔融方法制备了PA 6/POE/粘土纳米复合材料.PA 6/POE/粘土纳米复合材料具有良好的力学性能,其缺口冲击强度比PA 6有显著提高.研究结果表明,有机粘土剥离于PA 6基体中,POE相以岛状结构均匀分散于PA 6基体中;PA 6/POE/粘土纳米复合材料的储能模量比PA 6的低,并且随着有机粘土含量的增加而降低.PA 6/POE/粘土纳米复合材料的玻璃化转变温度(Tg)随着粘土含量的增加而升高,具有良好的热稳定性.

关 键 词:PA 6/POE/粘土纳米复合材料  力学性能  储能模量  热稳定性

Study on Morphology, Structure and Properties of Nylon 6/Ployolefin Elastomer/Clay Nanocomposites
ZHANG Chenggui,SUN Chunhong,ZHANG Xiaojing,JIA Tiangang,LI Yadong. Study on Morphology, Structure and Properties of Nylon 6/Ployolefin Elastomer/Clay Nanocomposites[J]. Materials Review, 2009, 23(14)
Authors:ZHANG Chenggui  SUN Chunhong  ZHANG Xiaojing  JIA Tiangang  LI Yadong
Abstract:Nylon 6/ployolefin elastomer/clay nanocomposites are prepared by melt blending. Mechanical testing results show that PA 6/POE/clay nanocomposites have better mechanical properties, especially, the impact strength of nanocomposites increases significantly. Organoclay plates are completely exfoliated in PA 6 matrix. From the SEM results, island POE domain homogeneously disperses in PA 6/POE/clay nanocomposites. Storage modulus of nanocomposites is lower than that of PA 6 and decreases with content of clay increasing. Glass transition temperature of nanocomposites is higher than that of PA 6 and increases with content of clay increasing. The nanocomposites have good thermal stability.
Keywords:PA 6/POE/clay nanocomposites  mechanical performance  storage modulus  thermal stability
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