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炭黑中性笔墨水书写性能的流变学表征
引用本文:钱纪军,陈爱平,刘众鑫,包友根,蒋中南,丁保中,孙宗元.炭黑中性笔墨水书写性能的流变学表征[J].精细化工,2009,26(5).
作者姓名:钱纪军  陈爱平  刘众鑫  包友根  蒋中南  丁保中  孙宗元
作者单位:1. 华东理工大学,材料科学与工程学院,超细材料制备与应用教育部重点实验室,上海,200237
2. 上海英雄,集团,有限公司,上海,201802
基金项目:上海市“曙光计划-技术难题攻关”项目(2005-15)~~
摘    要:测试了中性墨水的剪切应力随剪切速度变化的流变特性,并用Hersegel-Bulkley方程对流变曲线进行了拟合,提出了表征墨水书写性能的流变学参数。结果表明,中性笔墨水体系具有剪切变稀的流变特性,墨水书写性能可用流变参数综合表征,具有优良书写性能的中性笔墨水应该有较大的屈服应力(τ0)、强假塑性(n)和适中的触变性(s),即流变参数满足n<0.6、s=200~700和τ0=4.5~8.5 Pa等要求。在墨水应用性能的流变学表征分析的基础上,在13.33 kg/d规模中试装置上制备得到了书写性能与维可尼中性墨水相当的中试产品。

关 键 词:中性笔墨水  流变性能  书写性能  特种染料与颜料

The Rheological Characterization of the Writing Performance of Carbon Black Gel Ink
QIAN Ji-jun,CHEN Ai-ping,LIU Zhong-xin,BAO You-gen,JIANG Zhong-nan,DING Bao-zhong,SUN Zong-yuan.The Rheological Characterization of the Writing Performance of Carbon Black Gel Ink[J].Fine Chemicals,2009,26(5).
Authors:QIAN Ji-jun  CHEN Ai-ping  LIU Zhong-xin  BAO You-gen  JIANG Zhong-nan  DING Bao-zhong  SUN Zong-yuan
Affiliation:1.Key Lab for Ultrafine Materials of Ministry of Education;School of Materials Science & Engineering;East China University of Science & Technology;Shanghai 200237;China;2.Shanghai Hero Group Co.;Ltd.;Shanghai 201802;China
Abstract:The rheological properties of carbon black gel ink were investigated by measuring of the relationship between shear-stress and shear rate.The simulation of the rheological curve of gel ink samples with Hersegel-Bulkley equation was introduced.Further more the rheological parameters for characterizing the writing performance of gel ink were proposed.The results indicated that the gel ink was a system of strong shear-thinning performance.And the writing performance of the gel ink could be characterized with r...
Keywords:gel ink  rheological property  writing performance  special dyes and pigments  
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