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聚酯端羧基控制的改进
引用本文:朱国强.聚酯端羧基控制的改进[J].聚酯工业,2008,21(4):38-40.
作者姓名:朱国强
作者单位:中国石油乌鲁木齐石化公司化纤厂,新疆乌鲁木齐,830019
摘    要:从酯化和缩聚2个阶段分析了聚酯端羧基产生的原因。确定了工艺调整方案,通过提高酯化液位延长酯化停留时间来提高酯化率,降低缩聚反应温度尤其是终缩聚的温度减缓热降解反应,对降低产品端羧基值有一定效果。

关 键 词:聚酯  端羧基  控制

The improvement of the control of PET carboxyl end group value
ZHU Guo-qiang.The improvement of the control of PET carboxyl end group value[J].Polyester Industry,2008,21(4):38-40.
Authors:ZHU Guo-qiang
Affiliation:ZHU Guo-qiang (Chemical Fibre Plant of Urumqi Petrochemical Co. ,Urumqi 830019 ,China)
Abstract:The causes of the PET carboxyl end group were analysed from two stages esterification and polycondensation.The process adjustment plans were determined.The esterification rate was increased through increasing esterification liquid level,prolonging the esterification residence time.The thermal degradation was slow down by decreasing the polycondensation temperature especially the final polycondensation temperature.Better effects were obtained for decreasing the product carboxyl end group value.
Keywords:PET  carboxyl end group value  control
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