Highly selective low-temperature hydrogenation of furfuryl alcohol to tetrahydrofurfuryl alcohol catalysed by hectorite-supported ruthenium nanoparticles |
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| Affiliation: | 1. Institut de Chimie, Université de Neuchâtel, CH-2000 Neuchâtel, Switzerland;2. Service Analytique Facultaire, Université de Neuchâtel, CH-2000 Neuchâtel, Switzerland;1. Chemical Science and Engineering Division, Argonne National Laboratory, Argonne, IL 60439, USA;2. Energy Systems Division, Argonne National Laboratory, Argonne, IL 60439, USA;3. FRNY 2158, Purdue University, School of Chemical Engineering, Forney Hall of Chemical Engineering, 480 Stadium Mall Drive, West Lafayette, IN 47907-2100, USA;4. Nanotechnology Center, Purdue University, 1205, West Lafayette, IN 47907, USA;5. Center for Functional Nanomaterials, Brookhaven National Laboratory, Upton, NY 11973, USA;6. Department of Chemical and Biological Engineering, University of Wisconsin, Madison, WI 53706, USA;1. The Key Laboratory of Food Colloids and Biotechnology, Ministry of Education, School of Chemical and Material Engineering, Jiangnan University, Wuxi 214122, China;2. State Key Laboratory of Food Science & Technology, Wuxi 214122, Jiangsu, China;1. Key Laboratory of Materials Physics, Centre for Environmental and Energy Nanomaterials, Anhui Key Laboratory of Nanomaterials and Nanotechnology, CAS Center for Excellence in Nanoscience, Institute of Solid State Physics, Chinese Academy of Sciences, Hefei 230031, PR China;2. University of Science and Technology of China, Hefei, Anhui 230026, PR China;3. Centre for Clean Environment and Energy, Gold Coast Campus, Griffith University, Queensland 4222, Australia;1. School of Engineering, Brown University, Providence, RI 02912, USA;2. Department of Chemistry, Lakehead University, ON, Canada P7B 5E1 |
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| Abstract: | Metallic ruthenium nanoparticles intercalated in hectorite (particle size ~ 4 nm) were found to catalyse the hydrogenation of furfuryl acohol to give tetrahydrofurfuryl alcohol in methanolic solution under mild conditions. The best results were obtained at 40 °C under a hydrogen pressure of 20 bar (conversion 100%, selectivity > 99%). After a total turnover number of 1423, the hectorite supported ruthenium nanoparticles are deactivated but can be recycled and regenerated. |
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