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| 聚(2,5-二丁氧基)对苯乙炔的合成、表征及发光性能研究 | |
| 引用本文： | 哈斯乌力吉,黄宗浩,段雪梅,关宏宇,康博南,李光哲,王荣顺. 聚(2,5-二丁氧基)对苯乙炔的合成、表征及发光性能研究[J]. 功能材料, 2002, 33(4): 440-441 |
| 作者姓名： | 哈斯乌力吉 黄宗浩 段雪梅 关宏宇 康博南 李光哲 王荣顺 |
| 作者单位： | 1. 东北师范大学化学学院功能材料化学研究所,吉林长春 130024 2. 东北师范大学化学学院功能材料化学研究所,吉林长春,130024;吉林大学集成光电子国家重点实验室,吉林长春,130022 3. 东北师范大学化学学院功能材料化学研究所,吉林长春,130024 4. 吉林大学集成光电子国家重点实验室,吉林长春,130022 |
| 基金项目： | 国家和教育部重点实验室访问学者基金资助项目 (教技司 (1 999) 1 53) |
| 摘 要： | 用强碱诱导的脱氯化氢法合成了发光聚合物聚（2，5－二丁氧基）对苯乙炔（PDBOPV），并与前聚物路线合成法进行了比较。脱氯化氢法具有反应时间短和产率高等优点，而且不需要进行高温处理，有利于相关器件的制备。用紫外、红外光谱和^1H-NMR对聚（2，5－二丁氧基）对苯乙进行了表征，测定了荧光（PL）光谱，讨论了烷氧基取代对聚合物光学性质和可溶性的影响。 |
| 关 键 词： | 发光性能 发光聚合物 脱氯化氢法 荧光光谱 聚对苯乙炔 |
| 文章编号： | 1001-9731(2002)04-0440-02 |
| 修稿时间： | 2001-07-10 |
Syntheseis, characterization and luminescence property of poly [2,5-dibutoxy-p-phenylene-vinylene] |
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| HASI Wu li ji ,HUANG Zong hao ,,DUAN Xue mei ,GUAN Hong yu ,KANG Bo nan ,LI Guang zhe ,WANG Rong shun. Syntheseis, characterization and luminescence property of poly [2,5-dibutoxy-p-phenylene-vinylene][J]. Journal of Functional Materials, 2002, 33(4): 440-441 | |
| Authors: | HASI Wu li ji HUANG Zong hao DUAN Xue mei GUAN Hong yu KANG Bo nan LI Guang zhe WANG Rong shun |
| Affiliation: | HASI Wu li ji 1,HUANG Zong hao 1,2,DUAN Xue mei 1,GUAN Hong yu 1,KANG Bo nan 2,LI Guang zhe 1,WANG Rong shun 1 |
| Abstract: | Luminescence polymer poly[2,5 dibutoxy p phenylene vinylene] was synthesized through dehydrochlorination induced by strong base. Compared with the precursor route, the former has special advantages,such as the period of the synthesis was shorter, the yield of product was higher, and the high temperature processing wasn't mecessary, that's favorable to manufacturing relative device. The structure of poly [2,5 dibutoxy p phenylene vinylene] was characterized by IR, UV spectra and 1H NMR, also the photoluminescence spectrum was determined and the effect of alkoxy substituents on fluorescence properties and solubility of polymer was discussed. |
| Keywords: | poly [2 5 dibutoxy p phenylene vinylene] luminescence polymer dehydrochlorination photo luminescence spectra |
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