| NaBH_4/I_2体系还原4-正丙基环己基甲酸 |
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| 引用本文： | 朱生勃,刘骞峰,李启贵,冯震,刘慧琴.NaBH_4/I_2体系还原4-正丙基环己基甲酸[J].化工时刊,2008,22(11):31-32. |
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| 作者姓名： | 朱生勃 刘骞峰 李启贵 冯震 刘慧琴 |
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| 作者单位： | 1. 西安建筑科技大学理学院,陕西,西安,710055
2. 幸西安瑞联近代电子材料有限责任公司,陕西,西安,710065 |
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| 摘 要： | 介绍了NaBH4/I2体系还原4-正丙基环己基甲酸为4-正丙基环己基甲醇。从环境、温度、料比、溶剂量等因素分析得出了最佳反应条件。按此条件放大15倍,4-正丙基环己基甲酸的转化率达99.06%,4-正丙基环己基甲醇的收率为93.4%。
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| 关 键 词： | NaBH4/I2 体系还原反应 4-正丙基环己基甲酸 |
Reducing 4-propylcyclohexanecarboxylic Acid with NaBH4/I2 System |
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| Zhu Shengbo,Liu Qianfeng,Li Qigui,Feng Zhen,Liu Huiqin.Reducing 4-propylcyclohexanecarboxylic Acid with NaBH4/I2 System[J].Chemical Industry Times,2008,22(11):31-32. |
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| Authors: | Zhu Shengbo Liu Qianfeng Li Qigui Feng Zhen Liu Huiqin |
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| Affiliation: | Zhu Shengbo, Liu Qianfeng, Li Qigui, Feng Zhen, Liu Huiqin (School of Sciences, Xi＇ an University of Architecture and Technology, Shanxi Xi＇ an 710055; ＊ Xi＇ an Ruilian Modern Electronic Chemicals Co. , Ltd, Shanxi Xi＇ an 710065) |
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| Abstract: | Reduction of 4 - propylcyclohexanecarboxylic acid to （4 - propylcyclohexyl） methanol was introduced with NaBH4/I2 system. The best conditions from the environment, temperature, feedstock ratio and the amount of solvent were determined. The conversion of 4 - propylcyclohexaneearboxylic acid could reach to 99.06%, and the yield of（4 -propylcyclohexyl）methanol was 93.4% when magnified by 15 times under the ootimum conditons. |
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| Keywords: | NaBH4/I2 system 4 -propylcyclohexanecarboxylic acid reductive reaction |
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