| 塑料制品中多环芳烃的高效液相色谱法测定 |
| |
| 引用本文： | 余淑媛,王宏菊,杨左军,李彬,刘丽,王成云.塑料制品中多环芳烃的高效液相色谱法测定[J].塑料科技,2007,35(10):86-90. |
| |
| 作者姓名： | 余淑媛 王宏菊 杨左军 李彬 刘丽 王成云 |
| |
| 作者单位： | 深圳出入境检验检疫局,广东,深圳,518045 |
| |
| 摘 要： | 采用微波辅助萃取法提取塑料制品中的多环芳烃,并采用高效液相色谱法对其进行了测定。该方法所用色谱柱为多聚C18(LC-PAH)柱,流动相为乙腈/水,采用梯度淋洗方式,开始时为40%乙腈,28min后变为82%乙腈,48min后变成100%乙腈,保持8min。该方法的线性范围为0.099～200mg/L,线性相关系数为0.9993～0.9999,平均回收率为60.7%～109.8%,其相对标准偏差(RSD)为0.6%～8.8%,检出限(信噪比S/N=3)为0.05～0.1mg/kg,完全可以满足塑料制品中多环芳烃的检测要求。
|
| 关 键 词： | 多环芳烃 高效液相色谱法 塑料制品 |
| 文章编号： | 1005-3360（2007）10-0086-05 |
| 修稿时间： | 2007年8月15日 |
HPLC Determination of PAHs in Plastic Products |
| |
| Yu Shuyuan,Wang Hongju,Yang Zuojun,Li Bin,Liu Li,Wang Chengyun.HPLC Determination of PAHs in Plastic Products[J].Plastics Science and Technology,2007,35(10):86-90. |
| |
| Authors: | Yu Shuyuan Wang Hongju Yang Zuojun Li Bin Liu Li Wang Chengyun |
| |
| Affiliation: | Shenzhen Entry-Exit Inspection and Quarantine Bureau, Shenzhen 518045. China |
| |
| Abstract: | PHAs in plastic products were extracted by microwave-assist extraction, and a HPLC method was established to determine the contents of PAHs in plastic products. The analysis was carried out in a reversed-phase polymer C18 (LC-PAH) column by gradient elution with acetonitrile/ water as the mobile phase. The content of acetonitrile was 40% at the beginning , then changed to 82% after 28min, and varied to 100% after 48min, and maintained for 8min. The linear range was 0.099 to 200mg/L with coefficients of 0.9993 to 0.9999. The average recovery varied form 60.7% to 109.8%, and the relative standard derivation ranged from 0.6% to 8.8%. The limits of detection was 0.05 to 0.10mg/L at S/N=3. This method could satisfy the demand of analysis of PAHs in plastic products. |
| |
| Keywords: | PAHs HPLC Plastic product |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
|
