Hydrothermal synthesis,characterization and luminescent properties of GdPO4·H2O:Tb nanorods and nanobundles |
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Authors: | Hejuan Song Liqun Zhou Ling LiFei Hong Xinru Luo |
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Affiliation: | Ministry of Education Key Laboratory for the Synthesis and Application of Organic Functional Molecules, Hubei Collaborative Innovation Center for Advanced Organic Chemical Materials, College of Chemistry and Chemical Engineering, Hubei University, Wuhan 430062, PR China |
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Abstract: | In this paper, the Tb3+-doped GdPO4·H2O nanorods and nanobundles have been synthesized by the hydrothermal method with and without glycine, respectively. The X-ray powder diffraction (XRD), thermogravimetric and differential thermal analysis (TG–DTA), Fourier transform infrared spectroscopy (FT-IR), transmission electron microscopy (TEM), energy-dispersive spectra (EDS) and photoluminescence (PL) were employed to characterize the as-obtained products. It was found that the addition of glycine and the pH value have crucial influences on the formation of the resulting morphologies and sizes. The possible formation mechanisms for GdPO4·H2O:Tb3+ nanorods and nanobundles were put forward. A detailed investigation on the photoluminescence of GdPO4·H2O:Tb3+ different samples revealed that the luminescent properties of products are strongly correlated with the morphologies, sizes, coordination environment and crystal field symmetry. |
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Keywords: | A. Nanostructures C. X-ray diffraction D. Luminescence |
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