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改性PVDF催化膜的制备及其表征
引用本文:周江红,吴培瑛,张丽,曹天静,杨榕,张瑛洁.改性PVDF催化膜的制备及其表征[J].东北电力学院学报,2011(2):27-31.
作者姓名:周江红  吴培瑛  张丽  曹天静  杨榕  张瑛洁
作者单位:中国铝业中州分公司热电厂;东北电力大学化学工程学院;
基金项目:国家自然基金(50978067); 东北电力大学博士科研启动基金(No.BSJXM-200904)
摘    要:本文通过对PVDF膜进行接枝、磺化和离子交换负载铁,制备了PVDF催化膜,对其制备条件进行优化,对水通量、截留率、亲水性等性能进行了表征.实验结果表明PVDF膜的接枝率随着KOH浓度和碱处理时间的增加,PVDF膜的接枝率先增加后减小;而随着反应温度以及四丁基溴化铵(TB-AB)增加,PVDF膜的接枝率增大;膜的磺化度随...

关 键 词:PVDF膜  催化膜  接枝  磺化  水通量

Preparation and characteristics of modified PVDF catalytic membrane
ZHOU Jiang-hong,WU Pei-ying,ZHANG Li,CHAO Tian-jing,YANG Rong,ZHANG Ying-jie.Preparation and characteristics of modified PVDF catalytic membrane[J].Journal of Northeast China Institute of Electric Power Engineering,2011(2):27-31.
Authors:ZHOU Jiang-hong  WU Pei-ying  ZHANG Li  CHAO Tian-jing  YANG Rong  ZHANG Ying-jie
Affiliation:ZHOU Jiang-hong1,WU Pei-ying2,ZHANG Li2,CHAO Tian-jing2,YANG Rong2,ZHANG Ying-jie2(1.Zhongzhou Thermal Power Plant,Chinese Aluminium Industry,Jiaozuo Henan 454174,2.School of Chemical Engineering,Northeast Dianli University,Jilin Jilin 132012)
Abstract:PVDF catalytic membrane was prepared by grafting,sulfonating and ion-exchanging of PVDF membrane.The optimal conditions of the preparation were discussed and the characteristics of PVDF catalytic membrane was characterized by water flux,rejection rate and hydrophilicity.The results showed that the grafting rate of membrane increased and then decreased with the increase of concentration of KOH and the time of KOH,but it increased with the increase of reaction temperature and the content of TBAB added;the sul...
Keywords:PVDF membrane  Catalytic membrane  Grafting  Sulfonating  Water flux  
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