Hydroformylation of olefins using dispersed molecular catalysts on solid supports |
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| Authors: | N S Pagar R M Deshpande R V Chaudhari |
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| Affiliation: | (1) Homogeneous Catalysis Division, National Chemical Laboratory, 411008 Pune, India |
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| Abstract: | A new method for heterogenization of metal complex catalysts by precipitation of its water–soluble analogue as a Gr.2 metals
(Ca, Sr or Ba) salt on porous supports has been proposed. This technique yields a highly dispersed catalyst having a significantly
higher activity (TOF) for hydroformylation of olefins compared to other known heterogenized catalysts. The catalyst can be
recycled with ease. |
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| Keywords: | hydroformylation heterogenization rhodium olefins carbon support |
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