Zr-Cu-Ni非晶钎料真空钎焊TiAl合金/316L不锈钢接头的界面组织与剪切性能

采用自主设计制备的Zr-42.9Cu-21.4Ni非晶钎料对TiAl合金和316L不锈钢进行真空钎焊，研究钎焊温度和钎焊时间对TiAl合金/316L不锈钢异种金属接头微观组织和剪切性能的影响。结果表明：钎缝界面可以划分为6个不同的反应层。1040 ℃/10 min下制备的钎焊接头从TiAl合金到316L不锈钢侧界面组织依次为γ(TiAl)+AlCuTi/α₂(Ti₃Al)+AlCuTi/AlCu+ZrCuNi+FeZr/Cu₈Zr₃+ZrCuNi+TiFe+Fe₂Zr/FeZr+Fe₂Zr+TiFe₂+ZrCu/α-(Fe, Cr)。随着钎焊温度的升高，接头的抗剪强度先升高后降低。当钎焊温度为1040 ℃和钎焊时间25 min时，接头抗剪强度达到最大值162 MPa。断口分析表明，接头在FeZr+Fe₂Zr+TiFe₂+ZrCu界面处萌生，沿着Cu₈Zr₃+ZrCuNi+TiFe+Fe₂Zr和α-(Fe, Cr)扩展，呈解理断裂。

Interfacial microstructure and shear properties of vacuum brazing TiAl alloy/316L stainless steel j oint with Zr-Cu-Ni amorphous filler metal

Vacuum brazing of TiAl alloy and 316L stainless steel (SS) was conducted using Zr-42.9Cu-21.4Ni amorphous filler metal. The effect of brazing temperature and brazing time on the microstructure and shear properties of the dissimilar metal joints between TiAl alloy and 316L stainless steel was investigated. The results show that the interface of the brazed joint can be divided into six different reaction layers. The microstructure of the brazed joints from TiAl alloy to 316L stainless steel at 1040 ℃/10 min is γ(TiAl)+AlCuTi/α₂(Ti₃Al)+AlCuTi/AlCu+ZrCuNi+FeZr/Cu₈Zr₃+ZrCuNi+TiFe+Fe₂Zr/FeZr+Fe₂Zr+TiFe₂+ZrCu/α-(Fe, Cr). With the increase of brazing temperature, the shear strength of brazed joints increase first and then decrease. The maximum shear strength of 162 MPa is obtained at 1040 ℃/25 min. Fracture analysis indicates that cracks initiate at the interface of FeZr+Fe₂Zr+TiFe₂+ZrCu, and then propagate along Cu₈Zr₃+ZrCuNi+TiFe+Fe₂Zr and α-(Fe, Cr) with cleavage fracture pattern.