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活性炭载羟基铁协同H2O2类芬顿降解活性艳红X-3B
引用本文:李冰,李金秀,张丽,胡超,文水平,吴锦华.活性炭载羟基铁协同H2O2类芬顿降解活性艳红X-3B[J].印染,2022(2):59-63.
作者姓名:李冰  李金秀  张丽  胡超  文水平  吴锦华
作者单位:广东职业技术学院轻工与材料学院;华南理工大学环境与能源学院
基金项目:广州科技计划项目(201803030036);广东职业技术学院校级科研项目(XJKY2021021)。
摘    要:以活性炭为媒介,采用浸渍法制备了活性炭载羟基铁催化材料(FeOOH@AC),并协同双氧水类芬顿降解活性艳红X-3B染料。在pH=7、FeOOH@AC质量浓度1 g/L、H2O2浓度10 mmol/L的反应条件下,FeOOH@AC+H2O2体系对活性艳红X-3B的降解率达98.2%,相较AC和FeOOH@AC体系提高了17.2和3.7倍。初始pH试验表明,对活性艳红X-3B,FeOOH@AC+H2O2体系不仅在酸性条件下具有很好的降解能力,在碱性条件下(pH=9)的降解率可达83.6%,表现出较宽的pH适用范围。另外,4次循环试验后,FeOOH@AC对活性艳红X-3B的降解率仍大于60%。对其用盐酸洗脱并重新负载FeOOH,可再生。

关 键 词:废水处理  类芬顿反应  羟基铁  活性炭  活性艳红X-3B

Fenton-like degradation of Reactive Brilliant Red X-3B by activated carbon-supported hydroxyl iron and H2O2
LI Bing,LI Jinxiu,ZHANG Li,HU Chao,WEN Shuiping,WU Jinhua.Fenton-like degradation of Reactive Brilliant Red X-3B by activated carbon-supported hydroxyl iron and H2O2[J].Dyeing and Finishing,2022(2):59-63.
Authors:LI Bing  LI Jinxiu  ZHANG Li  HU Chao  WEN Shuiping  WU Jinhua
Affiliation:(School of Light Industry and Materials,Guangdong Polytechnic,Foshan 528041,China;School of Environment and Energy,South China University of Technology,Guangzhou 510006,China)
Abstract:Using activated carbon as a medium,an activated carbon-supported goethite catalyst material(FeOOH@AC)is prepared by impregnation method.It is used to Fenton-like degradation of Reactive Brilliant Red X-3B in corperation with H2O2.Under the reaction conditions of pH of 7,FeOOH@AC 1 g/L,H2O210 mmol/L,the degradation rate of Reactive Brilliant Red X-3B by FeOOH@AC+H2O2 system reaches 98.2%,which is 17.2 and 3.7 times higher than that of AC and FeOOH@AC system.The initial pH experiment shows that for Reac?tive Brilliant Red X-3B,the FeOOH@AC+H2O2 system not only has good degradation ability under acidic condi?tions,but also has a degradation rate of 83.6%under alkaline conditions(pH=9),showing a wide range of pH use.Additionally,after 4 cycle experiments,the degradation rate of Reactive Brilliant Red X-3B is still higher than 60%.It can be regenerated by washing away with hydrochloric acid and reloading with FeOOH.
Keywords:wastewater treatment  Fenton-like proess  goethite  activated carbon  Reactive Brilliant Red X-3B
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