Synthesis of Ni/TiO2 catalyst by sol-gel method for hydrogen production from sodium borohydride |
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Affiliation: | Department of Chemical Engineering, Engineering Faculty, Eski?ehir Technical University, Eski?ehir, 26555, Turkey |
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Abstract: | Hydrogen is a sustainable, renewable and clean energy carrier that meets the increasing energy demand. Pure hydrogen is produced by the hydrolysis of sodium borohydride (NaBH4) using a catalyst. In this study, Ni/TiO2 catalysts were synthesized by the sol-gel technique and characterized by X-ray diffraction (XRD), X-ray fluorescence spectroscopy (XRF), Fourier transform infrared spectroscopy (FT-IR), scanning electron microscopy (SEM) and Brunauer-Emmett-Teller (BET) methods. The effects of Ni loading ratio (20–40%), catalyst amount (75–200 mg), the concentration of sodium hydroxide (NaOH, 0.25–1 M), initial amount of NaBH4 (75–125 mg) and the reaction temperature (20–60 °C) on hydrogen production performance were examined. The hydrogen yield (100%) and hydrogen production rate (110.87 mL/gcat.min) were determined at the reaction conditions of 5 mL of 0.25 M NaOH, 100 mg NaBH4, 100 mg Ni/TiO2, 60 °C. Reaction order and activation energy were calculated as 0.08 and 25.11 kJ/mol, respectively. |
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Keywords: | Sodium borohydride Hydrogen Sol-gel Nanocatalyst Kinetic study |
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