Macromolecular crosslink of imidazole functionalized poly(vinyl alcohol) and brominated poly(phenylene oxide) for anion exchange membrane with enhanced alkaline stability and ionic conductivity

Anion exchange membranes (AEMs) are important energy conversion device for fuel cell applications, where the overall redox reaction happened. Both alkaline stability and ionic conductivity should be considered in the long-term use of fuel cells. In this work, imidazole functionalized polyvinyl alcohol was designed as the functional macromolecular crosslinking agent to fabricate crosslinked AEMs with brominated poly(phenylene oxide) matrix. Benefitting from the macromolecular crosslinked structure, the membranes displayed enhanced ionic conductivity and alkaline stability at elevated temperature. Moreover, membrane with ion exchange capacity of 1.54 mmol/g displayed ionic conductivity of 78.8 mS/cm at 80 °C, and the conductivity could maintain 75% of the initial value after immersion in 1 M NaOH solution at 80 °C for 1000 h. Moreover, a peak power density of 105 mW/cm² was achieved when the assembled single cell with c-91 was operated at 60 °C. These results indicated that the construction of macromolecular crosslinked AEMs have great potential in the practical application of anion exchange membranes fuel cells.