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Effect of chlorine exposure on the thermo-reflectance spectra of lead chalcogenide films
Authors:A.K. Sood  C.Y. Yang  J.E. Fischer
Affiliation:The Moore School of Electrical Engineering and Laboratory for Research on the Structure of Matter, University of Pennsylvania, Philadelphia, Penn. 19174, U.S.A.
Abstract:Small crystallites of PbCl2 have been observed on Cl2- and air-exposed surfaces of PbS. Identification has been made by observing the fundamental exciton of PbCl2 in thermoreflectance, and by the EDAX technique in a scanning electron microscope. Similar effects occur on PbSe and PbTe. The phenomenon may be applicable to a low level integrating chlorine detector.
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