Mesoporous Metal Fluoride Nanocomposite Films with Tunable Optical Properties Derived from Precursor Instability |
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Authors: | Dong In Kim Soonmin Yim Seulgi Ji Minsu Kim Seunghun Lee Minkyun Son Da Som Song Wooseok Song Taek-Mo Chung Sun Sook Lee Ki-Seok An |
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Affiliation: | 1. Thin Film Materials Research Center, Korea Research Institute of Chemical Technology, Daejeon, 34114 Republic of Korea;2. Department of Advanced Materials Engineering, Kyonggi University, Kyonggi University, Suwon, Kyonggi-Do, 16227 Republic of Korea |
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Abstract: | The precisely tailored refractive index of optical materials is the key to utilizing and manipulating light during its propagation through the matrix, thereby improving their application performances. In this paper, mesoporous metal fluoride films with engineered composition (MgF2:LaF3) are demonstrated to achieve finely tunable refractive indices. These films are prepared using a precursor-derived one-step assembly approach via the simple mixing of precursor solutions (Mg(CF3OO)2 and La(CF3OO)3); then pores are formed simultaneously during solidification owing to the inherent instability of La(CF3OO)3. The mesoporous structures are realized through Mg(CF3OO)2 and La(CF3OO)3 ions, which interacted with each other based on their electrostatic forces, providing a wide range of refractive indices (from 1.37 to 1.16 at 633 nm). Furthermore, it is systematically several MgF2(1-x)-LaF3(x) layers with different compositions (x = 0.0, 0.3, and 0.5) to form the graded refractive index coating that is optically consecutive between the substrate and the air for broadband and omnidirectional antireflection. An average transmittance of ≈98.03% (400–1100 nm) is achieved with a peak transmittance of ≈99.04% (at 571 nm), and the average antireflectivity is maintained at ≈15.75% even at an incidence of light of 65° (400–850 nm). |
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Keywords: | graded refractive index mesoporous films metal fluorides refractive index control solution process |
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