| Affiliation: | 1. Physics Department, Bar-Ilan University, Ramat Gan, 529002 Israel
Bar-Ilan Institute of Nanotechnology & Advanced Materials, Bar-Ilan University, Ramat Gan, 529002 Israel;2. Bar-Ilan Institute of Nanotechnology & Advanced Materials, Bar-Ilan University, Ramat Gan, 529002 Israel;3. Physics Department, Bar-Ilan University, Ramat Gan, 529002 Israel |
| Abstract: | Oil-in-water emulsion droplets spontaneously adopt, below some temperature Td, counterintuitive faceted and complex non-spherical shapes while remaining liquid. This transition is driven by a crystalline monolayer formed at the droplets' surface. Here, we show that ppm-level doping of the droplet's bulk by long-chain alcohols allows tuning Td by >50 °C, implying formation of drastically different interfacial structures. Furthermore, “magic” alcohol chain lengths maximize Td. This we show to arise from self-assembly of mixed alcohol:alkane interfacial structures of stacked alkane layers, co-crystallized with hydrogen-bonded alcohol dimers. These structures are accounted for theoretically and resolved by direct cryogenic transmission electron microscopy (cryoTEM), confirming the proposed structures. The discovered tunability of key properties of commonly-used emulsions by minute concentrations of specific bulk additives should benefit these emulsions' technological applicability. |
