Liquid-in-Aerogel Porous Composite Allows Efficient CO2 Capture and CO2/N2 Separation

The pursuit of efficient CO₂ capture materials remains an unmet challenge. Especially, meeting both high sorption capacity and fast uptake kinetics is an ongoing effort in the development of CO₂ sorbents. Here, a strategy to exploit liquid-in-aerogel porous composites (LIAPCs) that allow for highly effective CO₂ capture and selective CO₂/N₂ separation, is reported. Interestingly, the functional liquid tetraethylenepentamine (TEPA) is partially filled into the air pockets of SiO₂ aerogel with left permanent porosity. Notably, the confined liquid thickness is 10.9–19.5 nm, which can be vividly probed by the atomic force microscope and rationalized by tailoring the liquid composition and amount. LIAPCs achieve high affinity between the functional liquid and solid porous counterpart, good structure integrity, and robust thermal stability. LIAPCs exhibit superb CO₂ uptake capacity (5.44 mmol g^?1, 75 °C, and 15 vol% CO₂), fast sorption kinetics, and high amine efficiency. Furthermore, LIAPCs ensure long-term adsorption–desorption cycle stability and offer exceptional CO₂/N₂ selectivity both in dry and humid conditions, with a separation factor up to 1182.68 at a humidity of 1%. This approach offers the prospect of efficient CO₂ capture and gas separation, shedding light on new possibilities to make the next-generation sorption materials for CO₂ utilization.