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不同温度条件下煤对瓦斯的等温吸附实验研究
引用本文:张翔,陶云奇. 不同温度条件下煤对瓦斯的等温吸附实验研究[J]. 煤炭工程, 2011, 0(4): 87-89
作者姓名:张翔  陶云奇
作者单位:1. 中国矿业大学应用技术学院,江苏徐州,221008
2. 永城煤电控股集团有限公司博士后科研工作站,河南永城,476641;重庆大学西南资源开发及环境灾害控制工程教育部重点实验室,重庆,400044
基金项目:国家自然科学基金资助项目,国家科技重大专项项目,国家自然科学基金重点项目
摘    要: 为探索Langmuir方程吸附常数与温度之间的变化规律,利用HCA型高压容量法吸附装置,针对重庆能源投资集团松藻煤电公司8#煤层煤样,分别在温度为30℃、40℃、50℃、60℃、70℃条件下进行了煤对瓦斯的等温吸附实验。结果表明,当温度一定时,吸附量随瓦斯压力的升高逐渐增加并趋于一稳定值;压力一定时,随着温度的升高,煤的瓦斯吸附量呈下降趋势;而且,随着温度的升高,吸附常数a值有逐渐降低趋势,而b值明显呈线性关系显著下降;吸附常数a、b与温度T的分别符合二次函数和线性方程关系。

关 键 词:温度  瓦斯  吸附常数
收稿时间:2010-11-27;

Experiment Study on Gas Isothermal Adsorption from Coal Under Different Temperature Conditions
ZHANG Xiang,TAO Yun-qi. Experiment Study on Gas Isothermal Adsorption from Coal Under Different Temperature Conditions[J]. Coal Engineering, 2011, 0(4): 87-89
Authors:ZHANG Xiang  TAO Yun-qi
Abstract:To study the relationship between absorption constants in Langmuir equation and temperature, isothermal adsorption experiments with a temperature of 30℃, 40℃, 50℃, 60℃ and 70℃are carried out.. The equipment used in the experiments is HCA high pressure volumetric method gas adsorption experimental system, and the coal sample is got from the 8# coal-bed of Chongqing Energy Investment group Songzao C&;E CO. LTD.. The experimental results show that when temperature keeps constant, adsorption capacity will increase with the increase of gas pressure and it tends to be a stable value; when gas pressure keeps constant, the adsorption constant a will decrease with the increase of temperature, the adsorption constant b will decrease linearly with the increase of temperature; a and b respectly have a quadratic function relationship and a linear relationship with temperature T.
Keywords:temperature  gas  absorption constant
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