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PA66/POE-g-MAH/纳米SiO_2复合材料的制备及性能
引用本文:刘珊,王国全,曾晓飞,崔巧丽,陈建峰.PA66/POE-g-MAH/纳米SiO_2复合材料的制备及性能[J].塑料,2010,39(1).
作者姓名:刘珊  王国全  曾晓飞  崔巧丽  陈建峰
作者单位:北京化工大学,材料科学与工程学院,教育部超重力工程研究中心,北京,100029
摘    要:通过熔融共混的方法制备PA66/POE-g-MAH/纳米SiO_2三元共混体系,研究纳米SiO_2、POE-g-MAH对PA66力学性能的影响.研究结果表明:POE-g-MAH与纳米SiO_2对PA66有协同增韧效应,当PA66/POE-g-MAH/纳米SiO_2配比为100/30/0.1时,复合体系的缺口冲击强度达到最大,为纯PA66的10.9倍,为PA66/POE-g-MAH(100/30)二元体系的1.8倍;低温缺口冲击强度也达到最大,为纯PA66的6.3倍.用扫描电镜观察分析冲击断口形态.

关 键 词:纳米SiO_2  马来酸酐接枝乙烯-1-辛烯共聚物  熔融共混  协同增韧

Preparation, Mechanical Property and Morphology of PA66/POE-g-MAH/Nano-SiO_2 Composite
LIU Shan,WANG Guo-quan,ZENG Xiao-fei,CUI Qiao-li,CHEN Jian-feng.Preparation, Mechanical Property and Morphology of PA66/POE-g-MAH/Nano-SiO_2 Composite[J].Plastics,2010,39(1).
Authors:LIU Shan  WANG Guo-quan  ZENG Xiao-fei  CUI Qiao-li  CHEN Jian-feng
Abstract:PA66/POE-g-MAH/nano-SiO_2 compasite was prepared by melt blending. The effects of nano-SiO_2 andPOE-g-MAH on the mechanical property of PA66/POE-g-MAH/nan-SiO_2 composite were studied. The results showed thatnano-SiO_2 and POE-g-MAH had a synergetic toughening effect on PA66. The impact strength of PA66/POE-g-MAH/nano-SiO_2reached the maximum, which was about 10.9 times as high as that of PA66 and 1. 8 times as high as that ofPA66/POE-g-MAH (100/30),when the mass ratio of PA66/POE-g-MAH/nano-SiO_2 composite was 100/30/0.1.The impactstrength of the composite at low temperature was also greatly improved, the maximum was about 6. 3 times as high as that ofPA66. The impact fracture of composite was studied by SEM.
Keywords:PA66  PA66  nano-SiO_2  ethylene-octenecopolymer-grafted-maleic anhydride  melt blending  synergetic toughening
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