| 聚醚多元醇中微量单体含量的毛细管气相色谱分析 |
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| 引用本文： | 张庆秋,王文浩,李新豪,贾利亚,高宝柱.聚醚多元醇中微量单体含量的毛细管气相色谱分析[J].化学推进剂与高分子材料,2011,9(3):96-99. |
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| 作者姓名： | 张庆秋 王文浩 李新豪 贾利亚 高宝柱 |
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| 作者单位： | 黎明化工研究院,河南,洛阳,471000 |
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| 摘 要： | 采用气相色谱法测定聚醚多元醇中环氧丙烷单体的含量,以四氢呋喃为溶剂,使用DB-1(50 m×0.32 mm×0.25 μm)型分析柱,氢火焰离子化检测器,用内标法(甲醇为内标物)进行分析定量.微量单体测定结果的相对标准偏差＜10%,试验的回收率在(100±3)%以内,检测限低至4×10-6.该方法还具有分析速度快,准确...
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| 关 键 词： | 毛细管气相色谱法 聚醚多元醇 单体 内标法 |
Content Analysis of Trace Monomer in Polyether Polyol by Capillary Gas Chromatography |
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| ZHANG Qingqiu,WANG Wenhao,LI Xinhao,JIA Liya,GAO Baozhu.Content Analysis of Trace Monomer in Polyether Polyol by Capillary Gas Chromatography[J].Chemical Propellants & Polymeric Materials,2011,9(3):96-99. |
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| Authors: | ZHANG Qingqiu WANG Wenhao LI Xinhao JIA Liya GAO Baozhu |
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| Affiliation: | HANG Qingqiu,WANG Wenhao,LI Xinhao,JIA Liya,GAO Baozhu(Liming Research Institute of Chemical Industry,Luoyang 471000,China) |
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| Abstract: | The content of propylene oxide monomer in polyether polyol was determined by gas chromatography method and the quantitative analysis was carried out by internal standard method（methanol as internal standard substance） using tetrahydrofuran as solvent and using DB-1 analytical column（50mm×0.32mm×0.25μm） and hydrogen flame ionization detection（FID） device.The relative standard deviation for trace monomer detection is less than 10%.The test recovery yield is（100±3）% and the detection limit is low to 4×10-6.This method possesses the advantages of fast speed,accuracy and convenience,etc. |
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| Keywords: | capillary gas chromatography polyether polyol monomer internal standard method |
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