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一种新型喹啉衍生物的合成及其对Hg2+的检测
引用本文:郝会娟,周鑫,吴学. 一种新型喹啉衍生物的合成及其对Hg2+的检测[J]. 化学试剂, 2011, 33(6): 551-554
作者姓名:郝会娟  周鑫  吴学
作者单位:延边大学理学院,化学系,吉林延吉,133002
摘    要:以吡喃并喹啉为荧光团,吡咯啶二硫代甲酸铵为识别基团,合成了一种新的荧光探针分子,7-苯基-6H-吡喃[4,3-b]喹啉-2-吡咯啶二硫代乙酰胺.采用红外光谱、核磁共振谱和质谱对其结构进行了表征,并对其荧光性质进行了研究.结果表明,该化合物可以作为检测Hg2+的比率荧光探针,对于Hg2+有着很好的选择性及很高的灵敏度,在...

关 键 词:喹啉衍生物  汞离子  比率荧光探针

Synthesis of a novel quinoline derivatives and its application in recognition of mercury
HAO Hui-juan,ZHOU Xin,WU Xue. Synthesis of a novel quinoline derivatives and its application in recognition of mercury[J]. Chemical Reagents, 2011, 33(6): 551-554
Authors:HAO Hui-juan  ZHOU Xin  WU Xue
Affiliation:HAO Hui-juan,ZHOU Xin,WU Xue (Department of Chemistry,College of Science,Yanbian University,Yanji 133002,China)
Abstract:A novel fluorescent probe bearing 6H-chromeno quinoline fluorophore and methyl pyrrolidine-1-carbodithioate moieties was synthesized and charactered by FT-IR,TOF-MS and NMR.The properties of the fluorescent probe were investigated.The probe shows unique selectivity and high sensitivity to Hg2+ and it can detect Hg2+ ratiometrically without disturbed by other metal ions.
Keywords:quinoline derivatives  mercury ion  ratiometric fluorescent probe  
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