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An extreame disposition method for low-level radioactive wastes using supercritical water (3)
Authors:Wataru Sugiyama  Tomoo Yamamura  Ki Chul Park  Hiroshi Tomiyasu  Yoshinobu Shiokawa  Hidetsugu Okada  Yuji Sugita
Affiliation:

1Electric Power Research and Development Center, Chubu Electric Power Co., Inc., Kitasekiyama, Odaka-cho, Midori-ku, Nagoya 459-8522, Japan

2Institute for Materials Research, Tohoku University, Katahira, Aoba-ku, Sendai 980-8577, Japan

3Department of Chemistry and Material Engineering, Faculty of Engineering, Shinshu University, Wakasato, Nagano 380-8553, Japan

Abstract:Disposition of low-level radioactive wastes has been performed in supercritical water with RuO2 as a catalyst without the addition of any oxidizing materials. These wastes arose from nuclear power plants etc., constituting of nonflammable organic materials, such as fire resistant sheeting and rubber gloves. We investigated the distribution behavior of iron and cobalt attached to nonflammable organic materials, in solid, liquid and gas phases during the decomposition of this method. The distributions of these elements under various conditions (initial amounts) were determined by using their radioisotopes as simulated low-level radioactive wastes in order to ease the detection of trace amounts of elements even in solid and gas phases. Iron and cobalt were found only in the solid phase when non-radioactive iron hydroxide was added as a precipitation reagent before the supercritical-water reaction.
Keywords:Supercritical water  Low-level radioactive wastes  Disposition  Recovery of radioactivity as solids  Radiometric analysis
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