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| 离子液体中单乙二醇缩4,4′-双环己二酮的合成 | |
| 引用本文： | 杨会龙,刘宝友,赵地顺. 离子液体中单乙二醇缩4,4′-双环己二酮的合成[J]. 化学工程, 2010, 38(4) |
| 作者姓名： | 杨会龙 刘宝友 赵地顺 |
| 作者单位： | 1. 河北科技大学总务处,河北石家庄,050018;河北科技大学环境科学与工程学院,河北石家庄,050018 2. 河北科技大学环境科学与工程学院,河北石家庄,050018 3. 化学工程与制药学院,河北石家庄,050018 |
| 基金项目： | 国家自然科学基金资助项目(20576026);;河北省自然科学基金资助项目(B2008000670);;河北省教育厅计划项目(2008325);;河北科技大学杰出青年基金项目;;河北省环境工程重点学科经费资助项目 |
| 摘 要： | 以离子液体BM ImH2PO4为溶剂和催化剂,对重要薄膜晶体管(TFT)液晶中间体——单乙二醇缩4,4′-双环己二酮的合成进行了研究。结果表明,4,4′-双环己二酮与乙二醇在130℃下搅拌反应1 h,产物单乙二醇缩4,4双'-环己二酮的收率为68.7%,产物选择性为83.4%。离子液体法具有收率高,选择性好,产品分离容易,对环境友好等优点,具有工业应用价值。 |
| 关 键 词： | 离子液体 单乙二醇缩4,4′-双环己二酮 合成 |
Synthesis of bicyclohexane-4, 4'-dione mono-ethyleneketal in ionic liquid |
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| YANG Hui-long,,LIU Bao-you,ZHAO Di-shun. Synthesis of bicyclohexane-4, 4'-dione mono-ethyleneketal in ionic liquid[J]. Chemical Engineering, 2010, 38(4) | |
| Authors: | YANG Hui-long LIU Bao-you ZHAO Di-shun |
| Affiliation: | 1.Office of General Services;2.College of Environmental Science and Engineering;3.College of Chemical and Pharmaceutical Engineering;Hebei University of Science and Technology;Shijiazhuang 050018;Hebei Province;China |
| Abstract: | Bicyclohexane-4, 4'-dione mono-ethyleneketal, a key thin film transistor (TFT) liquid crystal intermediate, was synthesized with BMImH_2PO_4 as a solvent and catalyst. The results show that the reaction of bicyclohexane-4,4'-dione and glycol in BMImH_2PO_4 proceeds smoothly at 130℃ for 1 h to afford bicyclohexane-4,4'-dione mono-ethyleneketal with the yield of 68.7% and selectivity of 83.4%. The ionic liquid method is with the advantages of high yield and selectivity, ease of product separation, environmental benign and recycle of ionic liquid, and is significant for its promising industrial application. |
| Keywords: | ionic liquid bicyclohexane-4,4'-dione mono-ethyleneketal synthesis |
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