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| 新型FCC汽油两段加氢改质催化剂性能评价 | |
| 引用本文： | 刘燕来,钱颖,李淑清,王廷海,黄德华,吕龙刚,龚光碧.新型FCC汽油两段加氢改质催化剂性能评价[J].石油化工应用,2010,29(4):9-13. |
| 作者姓名： | 刘燕来 钱颖 李淑清 王廷海 黄德华 吕龙刚 龚光碧 |
| 作者单位： | 1. 中国石油大连石化公司,辽宁大连,116031 2. 中国科学院兰州化学物理研究所,甘肃兰州,730000;中国科学院研究生院,北京,100049;中国石油兰州化工研究中心,甘肃兰州,730060 3. 中国石油兰州化工研究中心,甘肃兰州,730060 |
| 基金项目： | 中国石油天然气股份有限公司科技管理部资助项目(06-03A-01-01-03) |
| 摘 要： | 在500 mL绝热评价装置上,将一段选择性加氢脱硫催化剂SDS和二段辛烷值恢复催化剂IADS串联,以中国石油大连石化公司全馏分FCC汽油为原料,进行两段加氢改质催化剂及工艺1 000 h性能考察和工艺条件优化。结果表明:在适宜的工艺条件下,全馏分FCC汽油经两段加氢改质后,烯烃体积分数由43.57%降到29.8%,芳烃体积分数由16.51%增加到23%,硫由125μg/g降到26.6μg/g,产品辛烷值损失小于0.2个单位。优化的工艺条件为:操作压力1.2～1.5MPa,液体空速2.0～3.5 h~(-1)(以SDS计),氢油体积比300～500,SDS入口温度180～220℃,IADS入口温度300～340℃。 |
| 关 键 词： | 选择加氢脱硫 辛烷值恢复 全馏分FCC汽油 两段加氢改质 |
Evaluation of the novel FCC gasoline two-stage hydro-upgrading catalysts |
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| LIU Yanlai,QIAN Ying,LI Shuqing,WANG Tinghai,HUANG Dehua,LV Longgang,GONG Guangbi.Evaluation of the novel FCC gasoline two-stage hydro-upgrading catalysts[J].Petrochemical Industry Application,2010,29(4):9-13. | |
| Authors: | LIU Yanlai QIAN Ying LI Shuqing WANG Tinghai HUANG Dehua LV Longgang GONG Guangbi |
| Affiliation: | 2/a>;3/a>;4;1.PetroChina Dianlian Petrochemical Company/a>;Dalian Liaoning 116031/a>;China/a>;2.Lanzhou Institute of Chemical Physics/a>;Chinese Academy of Sciences/a>;Lanzhou Gansu 730000/a>;3.Graduate University of Chinese Academy of Sciences/a>;Beijing 100049/a>;4. Lanzhou Petrochemical Research Center of PetroChina/a>;China |
| Abstract: | A study on 1000 h performance and process condition optimization of the two-stage hydro-upgrading catalysts was conducted on a 500 mL adiabatic unit combining the first stage selective hydrodesulfurization catalyst SDS and the second stage octane number restoration catalyst IADS(connection in series),using the full range FCC gasoline from PetroChina Dalian Petrochemical Company as the feedstock.The results showed that the olefin content dropped from 43.57%to 29.8%,aromatics content increased to 23%from 16.5... |
| Keywords: | selective hydrodesulfurization octane number restoration full range FCC gasoline two-stage hydro-upgrading |
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