Activated sludge-loaded polyvinyl alcohol microparticles for starch wastewater treatment in an airlift bioreactor |
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Authors: | Slobodan Cvetkovic Branko Bugarski Bojana Obradovic |
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Affiliation: | 1.Ministry of Environmental Protection of the Republic of Serbia,New Belgrade,Serbia;2.Faculty of Technology and Metallurgy,University of Belgrade,Belgrade,Serbia |
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Abstract: | Emulsification followed by freezing and thawing cycles was applied to produce poly(vinyl alcohol) (PVA) microparticles and to simultaneously immobilize activated sludge. Activity of the obtained microparticles (~400 μm in diameter) was evaluated in glucose syrup solutions and heat-pretreated wastewater from a starch factory by measurements of permanganate index (COD Mn ) reduction. The reaction followed first-order kinetics, revealing slight mass transfer limitations in PVA microparticles as determined from the kinetic rate constant that was ~35% lower than that in the freely suspended activated sludge culture. Yet, efficiency of the microparticles increased almost five-fold in a laboratory airlift bioreactor operating either in batch or continuous regimes. Over 19 days of operation under high organic loadings in the industrial wastewater (~100 kgCOD m?3 d?1), PVA microparticles (12.4% volume fraction) remained active and induced a decrease of over 90% of biodegradable COD Mn at the hydraulic retention time of 8 h. |
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