| 高固含量苯丙纳米乳液聚合研究 |
| |
| 引用本文： | 张文兴,张龙,李彦钧. 高固含量苯丙纳米乳液聚合研究[J]. 胶体与聚合物, 2005, 23(4): 14-17 |
| |
| 作者姓名： | 张文兴 张龙 李彦钧 |
| |
| 作者单位： | 长春工业大学化工学院,吉林长春,130012 |
| |
| 摘 要： | 合成了固含量40%、粒径50nm、分布0.050级别的纳米微胶乳,优选出了适宜的聚合工艺条件。依据正交试验法,比较了高固含量条件下乳化剂用量、引发剂用量及其加入方式、聚合温度、单体滴加速度等对微胶乳粒径及分布的影响,初步探讨了微乳液聚合机理。
|
| 关 键 词： | 高固含量 微乳液聚合 正交试验法 苯丙乳液 |
| 收稿时间： | 2005-08-27 |
| 修稿时间： | 2005-08-27 |
Study of high solid content St-acrylate microemulsion polymerization |
| |
| Zhang Wenxing,Zhang Long,Li Yanjun. Study of high solid content St-acrylate microemulsion polymerization[J]. Chinese Journal of Colloid and Polymer, 2005, 23(4): 14-17 |
| |
| Authors: | Zhang Wenxing Zhang Long Li Yanjun |
| |
| Affiliation: | School of chem. Eng. Changchun University of Tech. Changchun China 130012 |
| |
| Abstract: | 40G Solid content St-acrylate nanogel with average size 50nm and distribution 0. 050 particles were prepared, and polymerization parameters were optimized. Effects of emulsifier anount, initiator amount/feed method, polymerization tempreture and monomer dropping time under highsolid content condition on particle size and distribution were investigated with orthogonal experiments. Polymerization mechanism was also discussed. |
| |
| Keywords: | High-solid content Miciroemulsion polymerization Orthogonal experiment St-Acrylate |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
|
