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等离子体引发丝素在聚氨酯膜表面接枝的研究
引用本文:孙东豪,吴徵宇,李明忠,程辉铭,王红卫.等离子体引发丝素在聚氨酯膜表面接枝的研究[J].纺织学报,2005,26(3):4-7.
作者姓名:孙东豪  吴徵宇  李明忠  程辉铭  王红卫
作者单位:苏州大学材料工程学院 江苏苏州215021
基金项目:国家高技术研究发展计划(863计划);国家自然科学基金;纺织工程重点实验室基金
摘    要:将水分散型聚氨酯膜预浸渍处理后,采用低温等离子体技术,成功地制备了在表面接枝丝素蛋白或丝素肽的聚氨酯膜,并用SEM,ATR-FTIR和X-射线能谱分析了膜的表面性质。用丝素蛋白或丝素肽改性后,聚氨酯膜的表面亲水性提高;其力学性能和透汽性与聚氨酯底膜基本接近。

关 键 词:丝素  水分散型聚氨酯  等离子体  接枝
文章编号:0253-9721(2005)03-0004-04
收稿时间:1900-01-01;

Study on the graft copolymerization of silk fibroin onto the surface of polyurethane membranes initiated by plasma
SUN Dong-hao,WU Zheng-yu,LI Ming-Zhong,CHENG Hui-ming,WANG Hong-wei.Study on the graft copolymerization of silk fibroin onto the surface of polyurethane membranes initiated by plasma[J].Journal of Textile Research,2005,26(3):4-7.
Authors:SUN Dong-hao  WU Zheng-yu  LI Ming-Zhong  CHENG Hui-ming  WANG Hong-wei
Affiliation:School of Materials and Engineering;Soochow University;Suzhou;Jiangsu 215021;China
Abstract:After disproposed by pre-immersed water dispersive PU membranes,PU membranes grafted with the silk fibroin (SF) protein or the silk fibroin peptide(SP) protein were successfully prepared by the technique of plasma.The surface properties of the various membranes were analyzed by SEM,ATR-FTIR spectra and X-ray energy spectra.The results showed that after grafted with SF or SP protein,the hydrophilicity of PU membrane was improved,and the mechanical properties and water vapor permeabilities of the modified membranes were basically the same as that of PU membrane.
Keywords:silk fibroin  water dispersive polyurethane  plasma  grafting
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