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Assessment of the activities of catalysts for the hydrocracking of coal by means of hydrogen evolution
Authors:Tetsuro Yokono  Shigeru Shibata  Yuzo Sanada  H Hattori  K Tanabe
Affiliation:2. Coal Research Institute, Faculty of Engineering, Hokkaido University, Sapporo 060, Japan;1. Department of Chemistry, Faculty of Science, Hokkaido University, Sapporo 060, Japan
Abstract:A close relation has been found between hydrogen evolution from coal-catalyst and pitch-catalyst systems and catalytic activities of liquefaction reactions. A MoO3?TiO2 catalyst has the highest activity and the order of activity of the catalysts for hydrogen evolution is: MoO3?TiO3> MoO3?SiO2>10% Fe2O3TiO2?AI2O3>coal alone. The same trend was observed for benzene-soluble materials for the hydrocracking of Akabira Coal.
Keywords:coal  coal liquefaction  catalysis  dehydrogenation
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