| 稀土固体超强酸S2O^2- 8／ZrO2-PrO2-TiO2催化合成苯乙酸乙酯 |
| |
| 引用本文： | 尹荣,囫宣霖,杨春华,秦玉春,奚洪民,关晓辉.稀土固体超强酸S2O^2- 8／ZrO2-PrO2-TiO2催化合成苯乙酸乙酯[J].东北电力学院学报,2006,26(6):44-47. |
| |
| 作者姓名： | 尹荣 囫宣霖 杨春华 秦玉春 奚洪民 关晓辉 |
| |
| 作者单位： | [1]北华大学公共基础部,吉林吉林132013 [2]东北电力大学化学工程学院,吉林吉林132012 |
| |
| 摘 要： | 以稀土固体超强酸S2O^2- 8／ZrO2-PrO2-TiO2为催化剂，苯乙酸和乙醇为原料合成了苯乙酸乙酯。考察了催化剂用量、原料配比、反应时间等对酯化反应的影响。其最适宜反应条件：酸醇比为1：5、催化剂用量为1．5g（苯乙酸为0．1 mol）、反应时间为6h，在此条件下酯化率可达88％以上。表明固体超强酸S2O^2- 8／ZrO2-PrO2-TiO2具有良好的催化活性，它的使用可避免用浓硫酸催化所造成的环境污染，并可重复使用。
|
| 关 键 词： | 苯乙酸乙酯 稀土固体超强酸 酯化 |
| 文章编号： | 1005-2992（2006）06-0044-04 |
| 收稿时间： | 2006-08-31 |
| 修稿时间： | 2006年8月31日 |
Catalyzed Synthesis of Ethyl Phenylacetate by S2O^2- 8/ZrO2-PrO2-TiO2 Rare- earth Solid Superacid |
| |
| YIN Rong, HU Xuan-lin,YANG Chun-hua,XI Hong-min, GUAN Xiao-hui.Catalyzed Synthesis of Ethyl Phenylacetate by S2O^2- 8/ZrO2-PrO2-TiO2 Rare- earth Solid Superacid[J].Journal of Northeast China Institute of Electric Power Engineering,2006,26(6):44-47. |
| |
| Authors: | YIN Rong HU Xuan-lin YANG Chun-hua XI Hong-min GUAN Xiao-hui |
| |
| Affiliation: | 1. Department of Common Courses, Beihua University, Jilin City, 132013; 2. Chemical Engineering College, Nortllcast Dianli University, Jilin City, China, 132012 |
| |
| Abstract: | Ethyl phenylacetate was synthesized with phenylacetic acid and ethanol by rare-earth solid superacid S2O82-/ ZrO2-PrO2-TiO2 as catalyst.The influencing factors were examined including catalyst weight,molar ratio of phenylacetic acid to ethanol and reaction time.The results show that the appropriate conditions are as follow: n(phenylacetic acid):n(ethanol) =1:5,weight of catalyst 1.5 g(based on 0.1 mole phenylacetic acid),reaction time 6h.The yield of ethyl phenylacetate was about 88 %,in which the rare-earth solid superacid S2O82-/ ZrO2-PrO2-TiO2 satisfies catalytic activity for the reaction and the catalyst can be used repeatedly. |
| |
| Keywords: | Ethyl phenylacetate Rare- earth solid superacid Esterification |
| 本文献已被 CNKI 维普 等数据库收录！ |
|
