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Alkylation of Benzene with Propene on Beta Zeolites Under Supercritical Conditions
Authors:Xiangyan Meng  Zhangfeng Qin  Ye Zhang  Mei Dong  Jianguo Wang
Affiliation:(1) State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, P.O. Box 165, Taiyuan, 030001, Peoples Republic of China
Abstract:Alkylation of benzene with propene on a series of Beta zeolites under gaseous, liquid, vapor-liquid coexistence and supercritical conditions has been investigated. The highest yield of cumene and stability of the catalysts were observed when the reaction was carried out on Ga-modified H-Beta under supercritical conditions near the critical point, which may be ascribed to the effective dissolution and diffusion of the coke precursors deposited on the zeolites.
Keywords:alkylation  benzene  propene  Beta zeolite  supercritical conditions
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