Alkylation of Benzene with Propene on Beta Zeolites Under Supercritical Conditions |
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Authors: | Xiangyan Meng Zhangfeng Qin Ye Zhang Mei Dong Jianguo Wang |
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Affiliation: | (1) State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, P.O. Box 165, Taiyuan, 030001, Peoples Republic of China |
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Abstract: | Alkylation of benzene with propene on a series of Beta zeolites under gaseous, liquid, vapor-liquid coexistence and supercritical conditions has been investigated. The highest yield of cumene and stability of the catalysts were observed when the reaction was carried out on Ga-modified H-Beta under supercritical conditions near the critical point, which may be ascribed to the effective dissolution and diffusion of the coke precursors deposited on the zeolites. |
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Keywords: | alkylation benzene propene Beta zeolite supercritical conditions |
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