Preparation and mechanical properties of exfoliated CoAl layered double hydroxide (LDH)/polyamide 6 nanocomposites by in situ polymerization |
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Authors: | Hongdan Peng Wuiwui Chauhari Tjiu Lu Shen Shu Huang Chaobin He Tianxi Liu |
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Affiliation: | 1. State Key Laboratory of Mechanical Transmissions, College of Materials Science and Engineering, Chongqing University, Chongqing 400044, China;2. Research Centre of Laser Fusion, China Academy of Engineering Physics, Mianyang 621900, Sichuan, China;3. Engineering Research Center for Waste Oil Recovery Technology and Equipment of Ministry of Education, Chongqing Key Laboratory of Catalysis and New Environmental Materials, College of Environment and Resources, Chongqing Technology and Business University, Chongqing 400067, China;4. Guangdong Provincial Key Laboratory of Durability for Marine Civil Engineering, Shenzhen University, Shenzhen 518060, Guangdong, China;5. Research Center for Environmental Science & Technology, Institute of Fundamental and Frontier Sciences, University of Electronic Science and Technology of China, Chengdu 611731, Sichuan, China |
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Abstract: | Novel exfoliated nanocomposites based on polyamide 6 (PA6)/CoAl layered double hydroxide (CoAl-LDH) have been successfully prepared via in situ polymerization. X-ray diffraction (XRD) and transmission electron microscopy (TEM) results indicated that the inorganic nanoplatelets of CoAl-LDH were homogeneously dispersed in the PA6 matrix. Mechanical testing (by tensile tests and nanoindentation measurements) shows that, compared with neat PA6, the tensile modulus, the yield strength, and the hardness of the nanocomposites are substantially improved by about 100%, 75%, and 25%, respectively, with incorporating only 1 wt% CoAl-LDH. In addition, tensile fracture morphologies of neat PA6 and its nanocomposites are also compared and discussed. |
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