| 核壳型苯丙乳液的制备 |
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| 引用本文： | 龚雁,杨宏波,倪中斌,刘士荣. 核壳型苯丙乳液的制备[J]. 应用化工, 2009, 38(10) |
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| 作者姓名： | 龚雁 杨宏波 倪中斌 刘士荣 |
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| 作者单位： | 江南大学,化学与材料工程学院,江苏,无锡,214122 |
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| 摘 要： | 用种子乳液和预乳化工艺,以苯乙烯(St)、丙烯酸丁酯(BA)、甲基丙烯酸甲酯(MMA)、丙烯酸(AA)为单体,十二烷基硫酸钠(SDS)、烷基酚聚氧乙烯醚(OP-10)为混合乳化剂,过硫酸铵为引发剂,制备了具有核壳结构的苯丙乳液。探讨了乳化剂、引发剂、丙烯酸对乳液性能的影响。合适的反应条件为:MMA∶BA∶St∶AA=14∶25∶16∶2,乳化剂用量为3.2%,引发剂用量0.35%~0.42%,温度80℃。
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| 关 键 词： | 苯丙乳液 种子聚合 核壳结构 预乳化 |
Preparation of styrene-acrylic emulsion with core-shell structure |
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| Abstract: | The styrene-acrylate emulsion with core-shell structure was prepared by seed emulsion and pre-emulsification technology, taking styrene ( St) , buty-lacrylate ( BA ) , methyl methacrylate ( MMA ) , acrylic acid( AA) as copolymerization monomers,using alkylphenols polyoxyethylene (OP-10) and sodium dode-cyl sulfate(SDS) as emulsifiers and potassium persulfate as initiator. The effects of emulsifiers, initiator and AA on the emulsion performance were researched. The optimum conditions of the polymerization are: MMA :BA : St :AA = 14 :25 :16 :2,the amount of emulsifiers 3.2% , the amount of initiator 0.35% ～ 0.42%, reaction temperature 80℃. |
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| Keywords: | styrene-acrylic emulsion seed emulsion polymerization core-shell structure pre-emulsion |
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