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Relaxor‐like behaviors in Na1/2Bi1/2Cu3Ti4O12 ceramics
Authors:Chunchang Wang  Wei Ni  Xiaohong Sun  Le Wang  Can Wang  Kuijuan Jin
Affiliation:1. Laboratory of Dielectric Functional Materials, School of Physics & Material Science, Anhui University, Hefei, China;2. Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing, China
Abstract:Dielectric properties of Na1/2Bi1/2Cu3Ti4O12 ceramics were evaluated over the temperature range 300‐720 K. Two relaxor‐like dielectric anomalies were found. The low‐temperature anomaly was confirmed to be an oxygen‐vacancy‐related relaxation process. It is a pseudo‐relaxor behavior caused by a bulk relaxation and a Maxwell‐Wagner relaxation. The high‐temperature one was evidenced to be an electric ferroelectric phase‐transition process resulting from the oxygen‐vacancy ordering.
Keywords:dielectric relaxation  electronic ferroelectricity  Na1/2Bi1/2Cu3Ti4O12 ceramics  relaxor
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