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Thermodynamics of the Mg‐Mn‐O system—modeling and heat capacity measurements
Authors:David Dilner  Dmytro Pavlyuchkov  Tilo Zienert  Lina Kjellqvist  Olga Fabrichnaya
Affiliation:1. Materials Science and Engineering, KTH Royal Institute of Technology, Stockholm, Sweden;2. Institute of Materials Science, Technical University of Freiberg, Freiberg, Germany;3. Thermo‐Calc Software AB, Stockholm, Sweden
Abstract:In this study, a thermodynamic description of the Mg‐Mn‐O system is presented. Phase diagram data, structural information, and thermochemical data are used in the assessment. All solution phases are modeled using the compound energy formalism. In addition, heat capacity measurement of the MgMn2O4 and Mg6MnO8 phases are reported. The thermodynamic description reproduces thermochemical, structural, and phase diagram data.
Keywords:Calphad  heat capacity  metal‐matrix composite  Mg6MnO8  MgMn2O4  spinel
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