MO-LCAO-Berechnungen an Polymethinen. IX. Zur Farbigkeit gekoppelter Oxonol- und Cyaninfarbstoffe |
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Authors: | J. Fabian |
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Abstract: | MO-LCAO Calculations on Polymethines. IX. On the Chromaticity of Coupled Oxonol and Cyanine Dyes Streptopolymethines display low-energy electronic transitions with a high transition probability and possess, moreover, a high capability to accept or to release electrons. These properties account for the absorption colour of polymethine dyes consisting of two molecular fragments. Scope and limitations of a composite-molecule approach can be recognized by subjecting the electronic wavefunctions to the so-called configuration analysis. Colour-structure relationships are derived from inspection of key orbital interactions between the molecular fragments. |
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