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Luminescence and Preparation of LED Phosphor Ca8Mg ( SiO4)4Cl2 : Eu^2+
引用本文:杨萍,林建华,姚光庆.Luminescence and Preparation of LED Phosphor Ca8Mg ( SiO4)4Cl2 : Eu^2+[J].中国稀土学报(英文版),2005,23(5):633-635.
作者姓名:杨萍  林建华  姚光庆
作者单位:College of Chemistry and Molecular Engineering, State Key Laboratory of Rare Earth Materials Chemistry andApplications, Peking University, Beijing 100871, China
基金项目:Project supported by the National High-Tech Research Program of China (2001AA-ZB3103 )
摘    要:Calcium magnesium chlorosilicate doped by europium, Ca8Mg(SiO4)4Cl2: Eu^2+, was prepared by the solid state reaction at high temperature. The compound obtained is pure Ca8Mg(SiO4)4Cl2 phase with cubic structure. Its average particle size is 5 μm, and it has good dispersity and morphological form. The excitation spectrum of Ca8Mg(SiO4)4Cl2: Eu^2+ is a wide band, which covers from 270 to 480 nm. The emission spectrum is also a wide band peaked at 510 nm. The luminescent intensity reaches to the maximum when the concentration of Eu^2 + is 2%. The wavelength of emission and excitation of the phosphor with various Eu^2 + contents keeps constant. This spectrum range matches violet and blue LED chips very well, and its strong luminescence intensity is suitable for a green phosphor of tricolor phosphor of white light LED.

关 键 词:发光二极管  发光性能  稀土    三基色
文章编号:1002-0721(2005)05-0633-03
收稿时间:2005-04-10
修稿时间:2005-06-30
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