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Synthesis of Magnesium Aluminate Spinel Platelets from α-Alumina Platelet and Magnesium Sulfate Precursors
Authors:Shinobu Hashimoto  Shaowei Zhang  William Edward Lee  Akira Yamaguchi
Affiliation:Department of Engineering Materials, The University of Sheffield, Sheffield S1 3JD, United Kingdom
Abstract:Spinel platelets were formed from a powder mixture of 3–5 μm wide and 0.2–0.5 μm thick α-Al2O3 and 1–8 μm (average 3 μm) MgSO4 heated 2 h at 1200°C. The hexagonal platelet shape of the original α-Al2O3 platelet was maintained in the spinel, although their size was slightly increased and their surface roughened. When a mixture of α-Al2O3 platelets and MgO powder was heated 3 h at 1400°C, the spinel formed lost the platelet morphology of the alumina.
Keywords:spinels  alumina  refractories  synthesis
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