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Thermal properties and fire behaviour of materials produced from curing mixed epoxy and phenolic resins
Authors:J. M. Laza  E. Bilbao  M. T. Garay  J. L. Vilas  M. Rodríguez  L. M. León
Affiliation:1. Departamento de Química Física, Facultad de Ciencia y Tecnología, Universidad del País Vasco (UPV/EHU), Apartado 644, 48080 Bilbao, Spain;2. Departamento de Ingeniería Química y Medio Ambiente, Escuela Universitaria de Ingeniería Técnica Minera, Universidad del País Vasco (UPV/EHU), Colina de Beurko s/n, 48902‐Barakaldo, Spain
Abstract:Thermal stability and fire behaviour of materials obtained from curing mixed epoxy and phenolic resins have been studied, the decomposition processes being compared with those for the pure resins. Samples were cured by triethylenetetramine or p‐toluenesulphonic acid by isothermal pressing at 90°C, and decompositions were carried out under nitrogen and air environment from 50 to 1000°C. Only for mixtures with higher proportion of epoxy resin, the decomposition process goes through a unique step as for the pure resin. Results from fire tests indicated that mixtures are classified as M3 and F1. Copyright © 2008 John Wiley & Sons, Ltd.
Keywords:thermal stability  epoxy resin  phenolic resin  fire properties
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