首页 | 本学科首页   官方微博 | 高级检索  
     

废弃口罩基ZIF-8/Ag/TiO2复合材料的制备及其光催化降解染料性能
引用本文:张雅宁,张辉,宋悦悦,李文明,李雯君,姚佳乐.废弃口罩基ZIF-8/Ag/TiO2复合材料的制备及其光催化降解染料性能[J].纺织学报,2022,43(7):111-120.
作者姓名:张雅宁  张辉  宋悦悦  李文明  李雯君  姚佳乐
作者单位:1.西安工程大学 纺织科学与工程学院, 陕西 西安 7100482.西安工程大学 功能纺织材料研究中心, 陕西西安 7100483.西安工程大学 省部共建智能纺织材料与制品国家重点实验室(培育), 陕西 西安 710048
基金项目:大学生创新创业训练计划项目(S202010709035);陕西省国际科技合作计划项目(2020KW-069);国家自然科学基金面上项目(51873169)
摘    要:针对废弃口罩和印染废水处理难题,利用金属有机骨架ZIF-8高度可调的孔径、大的比表面积、优异的吸附和光催化活性,基于化学共沉淀法和煅烧技术制备出ZIF-8/Ag/TiO2异质结,并将其负载到废弃的口罩上。对颗粒物和口罩复合材料的形貌、结构、比表面积、键合状态、能带结构和热稳定性进行了分析,测定了吸附、光催化降解亚甲基蓝和刚果红染料性能。研究结果表明:较原始口罩,废弃口罩基ZIF-8/Ag/TiO2复合材料的吸附、可见光光催化降解亚甲基蓝染料能力分别提高了12.9倍和4.8倍,且可多次重复使用;较ZIF-8和ZIF-8/TiO2,ZIF-8/Ag/TiO2异质结吸附能力和可见光光催化活性增强。Ag掺杂ZIF-8/ZnO与C、N掺杂TiO2使得ZIF-8/Ag/TiO2异质结带隙变窄,且有孔的中空结构能够更加充分地吸收可见光。

关 键 词:废弃口罩  ZIF-8/Ag/TiO2异质结  吸附  光催化降解  染料  印染废水  废水处理  
收稿时间:2021-05-07

Preparation of discarded mask-based ZIF-8/Ag/TiO2 composite and its photocatalytic property for dye degradation
ZHANG Yaning,ZHANG Hui,SONG Yueyue,LI Wenming,LI Wenjun,YAO Jiale.Preparation of discarded mask-based ZIF-8/Ag/TiO2 composite and its photocatalytic property for dye degradation[J].Journal of Textile Research,2022,43(7):111-120.
Authors:ZHANG Yaning  ZHANG Hui  SONG Yueyue  LI Wenming  LI Wenjun  YAO Jiale
Affiliation:1. School of Textile Science and Engineering, Xi'an Polytechnic University, Xi'an, Shaanxi 710048, China2. Research Centre for Functional Textile Materials, Xi'an Polytechnic University, Xi'an, Shaanxi 710048, China3. State Key Laboratory of Intelligent Textile Material and Products, Xi'an Polytechnic University, Xi'an, Shaanxi 710048, China
Abstract:Aiming to use discarded masks for purifying printing and dyeing wastewater, ZIF-8/Ag/TiO2 heterojunction was prepared based on the chemical co-precipitation and calcination methods using metal organic framework ZIF-8 as the supporting material, making use of the characteristics of ZIF-8 being highly adjustable pore size, large specific surface area, excellent adsorption capability, and high photocatalytic activity. The synthesized ZIF-8/Ag/TiO2 particles were loaded on the surface of discarded mask. The morphology, structure, specific surface area, chemical bonding state, electronic energy band structure, and thermal stability of the resultant particles and mask-based composite were systemically characterized. The properties of adsorption and visible light photocatalytic degradation of methylene blue and Congo Red dyes were investigated. Experimental results indicated that in comparison with the untreated mask, the adsorption and photocatalytic degradation capabilities towards methylene blue by the mask-ZIF-8/Ag/TiO2 composite were improved by 12.9 and 4.8 times respectively with good reusability. ZIF-8/Ag/TiO2 heterojunction exhibited stronger adsorption capacity and visible light photocatalytic activity as compared with ZIF-8 and ZIF-8/TiO2. The band-gap of ZIF-8/Ag/TiO2 was narrowed due to the doping of Ag into ZIF-8/ZnO and the doping of C and N into TiO2. In addition, the hollow-structured ZIF-8/Ag/TiO2 with holes could absorb more visible lights.
Keywords:discarded mask  ZIF-8/Ag/TiO2 heterojunction  adsorption  photocatalytic degradation  dye  printing and dyeing wastewater  waste water treatment  
点击此处可从《纺织学报》浏览原始摘要信息
点击此处可从《纺织学报》下载全文
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号